91182-50-2

Basic information

• Product Name: 3-BROMO-2-PHENYLPYRIDINE
• Synonyms: 3-BROMO-2-PHENYLPYRIDINE;Pyridine, 3-bromo-2-phenyl-
• CAS NO: 91182-50-2
• Molecular Formula: C₁₁H₈BrN
• Molecular Weight: 234.09
• Mol File: 91182-50-2.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 296.1 °C at 760 mmHg
• Flash Point: 132.9 °C
• Appearance: /
• Density: 1.426 g/cm³
• Vapor Pressure: 0.00258mmHg at 25°C
• Refractive Index: 1.606
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 2.08±0.10(Predicted)
• CAS DataBase Reference: 3-BROMO-2-PHENYLPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMO-2-PHENYLPYRIDINE(91182-50-2)
• EPA Substance Registry System: 3-BROMO-2-PHENYLPYRIDINE(91182-50-2)

Safety Data

• Hazardous Substances Data: 91182-50-2(Hazardous Substances Data)

Usage

Physical Form

Solid

Uses

3-BROMO-2-PHENYLPYRIDINE is a useful research chemical.

InChI:InChI=1/C11H8BrN/c12-10-7-4-8-13-11(10)9-5-2-1-3-6-9/h1-8H

Upstream product

• 13534-89-9 2,3-dibromopyridine 
• 98-80-6 phenylboronic acid 
• 626-55-1 3-Bromopyridine 
• 52200-48-3 3-bromo-2-chloropyridine 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 

Downstream Products

• 485385-76-0 3-ethynyl-2-phenylpyridine 
• 1398509-70-0 2-phenyl-3-(2-phenylethynyl)pyridine 
• 639782-24-4 2-phenyl-3-(trifluoromethyl)pyridine 

Relevant articles and documents

Synthesis of 6-phenylbenzo[h]quinolinesviaphotoinduced dehydrogenative annulation of (E)-2-phenyl-3-styrylpyridines

A concise and environmentally friendly protocol was developed for the synthesis of 6-phenylbenzo[h]quinolines. 6-Phenylbenzo[h]quinolines were obtained in good yieldsviairradiation of (E)-2-phenyl-3-styrylpyridines with a 254 nm UV light (64 W) in EtOH under an argon atmosphere in the presence of TFA. The reaction is a dehydrogenative annulation reaction that proceeds through 6π-electrocyclization, a [1,5]-H shift, 1,3-enamine tautomerization, and elimination of a hydrogen molecule to afford 6-phenylbenzo[h]quinolines. The described protocol not only avoids the usage of a transition metal catalyst and an oxidant but also has the advantages of high atom efficiency and mild reaction conditions.

Syntheses of Benzofuranoquinolines and Analogues via Photoinduced Acceptorless Dehydrogenative Annulation of o-Phenylfuranylpyridines

A strategy for the syntheses of benzofuranoquinolines and its analogues via the irradiation of o-phenylfuranyl/thienylpyridines/pyrimidines in DCM with UV light at rt under an argon atmosphere is described. The mechanism of this reaction through the proce

Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides

An efficient cobalt catalyst system for the Suzuki-Miyaura cross-coupling reaction of arylboronic esters and aryl halides has been identified. In the presence of cobalt(II)/terpyridine catalyst and potassium methoxide, a diverse array of (hetero)biaryls have been prepared in moderate to excellent yields.