916320-82-6 Usage
Chemical Properties
White crystals
Uses
Reactant for preparation of:Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioestersHydroacylation reaction of aldehydes in Ionic liquid (IL) mediumDCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions
Check Digit Verification of cas no
The CAS Registry Mumber 916320-82-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,1,6,3,2 and 0 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 916320-82:
(8*9)+(7*1)+(6*6)+(5*3)+(4*2)+(3*0)+(2*8)+(1*2)=156
156 % 10 = 6
So 916320-82-6 is a valid CAS Registry Number.
InChI:InChI=1/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2/b20-19+
916320-82-6Relevant articles and documents
A convenient preparation of di-p-chlorobenzyl azodicarboxylate (DCAD) for mitsunobu couplings
Taft, Benjamin R.,Swift, Elizabeth C.,Lipshutz, Bruce H.
experimental part, p. 332 - 334 (2009/06/18)
Gram-scale synthesis of pure, bench-stable solid di-p-chlorobenzyl azodicarboxylate (DCAD) is performed in two steps without resorting to chromatography. This novel reagent effects Mitsunobu couplings with yields comparable to DEAD or DIAD, while addressi