91710-10-0Relevant articles and documents
Adducts of Arsenic(III), Antimony(III) and Bismuth(III) Trichlorides with Benzothiazolines
Chauhan, H. P. S.,Srivastava, G.,Mehrotra, R. C.
, p. 436 - 437 (2007/10/02)
Adducts of arsenic(III), antimony(III) and bismuth(III) trichlorides with benzothiazolines with the general formula, MCl3.R(R') (M = As, Sb, Bi, R = Me, R' = Me, Et, Ph, C6H4F; R = H, R' = Ph) have been synthesized by the reactions of the corresponding metal trichlorides with benzothiazoles in 1:1 molar ratio in suitable organic solvents at 0 to 5 deg C.These adducts are highly susceptible to hydrolysis even by atmospheric moisture and are insoluble in common organic solvents.IR spectral data indicate that coordination in these adducts occurs through nitrogen of benzothiazoline.