92149-04-7

Basic information

• Product Name: 2-isopropyl-1H-naphtho[2,3-d]imidazole-4,9-dione
• CAS NO: 92149-04-7
• Molecular Weight: 240.261
• Mol File: 92149-04-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-isopropyl-1H-naphtho[2,3-d]imidazole-4,9-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-isopropyl-1H-naphtho[2,3-d]imidazole-4,9-dione(92149-04-7)
• EPA Substance Registry System: 2-isopropyl-1H-naphtho[2,3-d]imidazole-4,9-dione(92149-04-7)

Safety Data

• Hazardous Substances Data: 92149-04-7(Hazardous Substances Data)

Upstream product

• 73882-22-1 2-Amino-3-(2',2'-dimethylaziridino)-1,4-naphthoquinone 

Relevant articles and documents

Acid-catalysed, Nucleophile-catalysed and Thermal Decomposition of 2-Amino-3-(2',2'-dimethylaziridino)-1,4-naphthoquinone

The course of the thermal, acid-catalysed and iodide-catalysed decomposition of 2-amino-3-(2',2'-dimethylaziridino)-1,4-naphthoquinone (III) was investigated.Thermal and iodide-catalysed decompositions gave mainly 2,3-diamino-1,4-naphthoquinone (VI) and 2-amino-3-(2'-methylallylamino)-1,4-naphthoquinone (V) together with low amounts of 2,2-dimethyl-1,2,3,4,5,10-hexahydrobenzoquinoxaline (IV) and 2-isopropyl-1H-naphthoimidazole-4,9-dione (VII).The acid catalysed isomerization of the aziridinonaphthoquinone III with halohydric acids or with acetic acid readily gave the opening of the aziridine ring; the corresponding salts of 2-amino-3-(2'-haloisobutylamino)-1,4-naphthoquinones (VIIIa-c) and 2-amino-3-(2'-acetoxyisobutylamino)-1,4-naphthoquinone (X) were formed by cleavage of the carbon-nitrogen bond at the substituted carbon atom.Hypotheses on the mechanism of these reactions are given.