92421-08-4

Basic information

• Product Name: Benzenepropanoic acid, b-hydroxy-a-(1-methylethenyl)-, methyl ester
• CAS NO: 92421-08-4
• Molecular Formula: C13H16O3
• Molecular Weight: 220.268
• Mol File: 92421-08-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, b-hydroxy-a-(1-methylethenyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, b-hydroxy-a-(1-methylethenyl)-, methyl ester(92421-08-4)
• EPA Substance Registry System: Benzenepropanoic acid, b-hydroxy-a-(1-methylethenyl)-, methyl ester(92421-08-4)

Safety Data

• Hazardous Substances Data: 92421-08-4(Hazardous Substances Data)

Upstream product

• 39652-45-4 (R)-2-((S)-Acetoxy-phenyl-methyl)-3-methyl-but-3-enoic acid methyl ester 
• 924-50-5 Methyl 3,3-dimethylacrylate 
• 100-52-7 benzaldehyde 
• 19041-17-9 methyl 4-bromo-3-methylbut-2-enoate 

Downstream Products

• 92421-10-8 (Z)-2-Carbomethoxy-3-methyl-1-phenyl-1,3-butadiene 
• 92421-09-5 (E)-2-Carbomethoxy-3-methyl-1-phenylbutadiene 
• 69637-31-6 (R)-2-((S)-Hydroxy-phenyl-methyl)-3-methyl-but-3-enoic acid 
• 77124-17-5 (E)-2-benzylidene-3-methylbutanoic acid 

Relevant articles and documents

Cleavage of Esters under Nearly Neutral Conditions at High Pressure. Chemo- and Regioselective Hydrolysis in Organic Solvents

Hydrolysis of esters proceeded at room temperature under high pressure in the presence of iPr2NEt or N-methylmorpholine using CH3CN-H2O (60:1) as the solvent.This very mild procedure enables the smooth hydrolysis of biologically important compounds such as amino esters, aliphatic unsaturated fatty esters, and β-hydroxy esters; no racemization, no isomerization, and no side reactions take place.

REGIOSELECTIVE CONTROL OF ALLYL ANIONS WITH CADMIUM CHLORIDE: α vs. γ CONDENSATION WITH ALDEHYDES

A general method for directing the condensation of allyl anions such as 2 with aldehydes preferentially to the γ position of the unsaturated nucleophile is described.The procedure employs cadmium chloride to control the regioselectivity and will facilitat