92674-39-0

Basic information

• Product Name: Pyrimidine, 5-(phenylmethyl)- (9CI)
• Synonyms: Pyrimidine, 5-(phenylmethyl)- (9CI)
• CAS NO: 92674-39-0
• Molecular Formula: C₁₁H₁₀N₂
• Molecular Weight: 170.2105
• Product Categories: QUINAZOLINE;PYRIMIDINE
• Mol File: 92674-39-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyrimidine, 5-(phenylmethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrimidine, 5-(phenylmethyl)- (9CI)(92674-39-0)
• EPA Substance Registry System: Pyrimidine, 5-(phenylmethyl)- (9CI)(92674-39-0)

Safety Data

• Hazardous Substances Data: 92674-39-0(Hazardous Substances Data)

Upstream product

• 4595-59-9 5-bromopyrimidine 
• 100-44-7 benzyl chloride 

Relevant articles and documents

Photo-Ni-Dual-Catalytic C(sp2)-C(sp3) Cross-Coupling Reactions with Mesoporous Graphitic Carbon Nitride as a Heterogeneous Organic Semiconductor Photocatalyst

The synergistic combination of a heterogeneous organic semiconductor mesoporous graphitic carbon nitride (mpg-CN) and a homogeneous nickel catalyst with visible-light irradiation at room temperature affords the C(sp2)-C(sp3) cross-co

Nickel-Catalyzed Cross-Electrophile Coupling with Organic Reductants in Non-Amide Solvents

Cross-electrophile coupling of aryl halides with alkyl halides has thus far been primarily conducted with stoichiometric metallic reductants in amide solvents. This report demonstrates that the use of tetrakis(dimethylamino)ethylene (TDAE) as an organic reductant enables the use of non-amide solvents, such as acetonitrile or propylene oxide, for the coupling of benzyl chlorides and alkyl iodides with aryl halides. Furthermore, these conditions work for several electron-poor heterocycles that are easily reduced by manganese. Finally, we demonstrate that TDAE addition can be used as a control element to ‘hold’ a reaction without diminishing yield or catalyst activity.