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935-30-8

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935-30-8 Usage

Uses

2-Azacyclononanone has been used as an internal standard liquid chromatography-ultraviolet detection method for the determination of caprolactam in the aqueous food stimulant 3% acetic acid (w/v).

General Description

2-Azacyclononanone forms complexes with hydrated lanthanides trifluoroacetate in ethanol. It reacts with mercury(II)acetate and erbium(III)nitrate in methanol to yield the heterocyclic complex .

Purification Methods

Dissolve it in CHCl3, decolorise it with charcoal, evaporate to dryness and recrystallise it from CHCl3/hexane. Sublime it at high vacuum. The oxime has m 117o (from *C6H6 or pet ether). [Guggisberg Helv Chim Acta 61 1050 1978, Olah et al. Synthesis 538 1979, Behringer & Meier Justus Liebigs Ann Chem 607 67 1957, Beilstein 21 III/V 3260.]

Check Digit Verification of cas no

The CAS Registry Mumber 935-30-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,3 and 5 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 935-30:
(5*9)+(4*3)+(3*5)+(2*3)+(1*0)=78
78 % 10 = 8
So 935-30-8 is a valid CAS Registry Number.
InChI:InChI=1/C8H15NO/c10-8-6-4-2-1-3-5-7-9-8/h1-7H2,(H,9,10)

935-30-8 Well-known Company Product Price

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  • Alfa Aesar

  • (A18621)  8-Octanolactam, 98%   

  • 935-30-8

  • 5g

  • 952.0CNY

  • Detail
  • Alfa Aesar

  • (A18621)  8-Octanolactam, 98%   

  • 935-30-8

  • 25g

  • 2296.0CNY

  • Detail
  • Alfa Aesar

  • (A18621)  8-Octanolactam, 98%   

  • 935-30-8

  • 100g

  • 7724.0CNY

  • Detail

935-30-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-AZACYCLONONANONE

1.2 Other means of identification

Product number -
Other names 2H-Azonin-2-one, octahydro-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:935-30-8 SDS

935-30-8Relevant articles and documents

A novel synthetic route of fused tricyclic framework quinoline derivatives from readily available aliphatic amino carboxylic acid substrates

Mohammed, Shireen

, p. 611 - 617 (2019/06/07)

A novel and an efficient strategy of fused tricyclic quinoline heterocycle compounds from aliphatic amino carboxylic acid substrates was studied. The protocol here is proceed over main reaction processes including: cyclization, protection, amidine formation, further cyclization and finally coupling with boronic acid substrate through Suzuki reaction. These reactions afforded the corresponding products in high yields. Furthermore, all synthesized compounds were identified by spectral data.

Synthesis of Cyclic Peptide Mimetics by the Successive Ring Expansion of Lactams

Stephens, Thomas C.,Lodi, Mahendar,Steer, Andrew M.,Lin, Yun,Gill, Matthew T.,Unsworth, William P.

supporting information, p. 13314 - 13318 (2017/10/05)

A successive ring-expansion protocol is reported that enables the controlled insertion of natural and non-natural amino acid fragments into lactams. Amino acids can be installed into macrocycles via an operationally simple and scalable iterative procedure, without the need for high dilution. This method is expected to be of broad utility, especially for the synthesis of medicinally important cyclic peptide mimetics.

Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement

Chang, Albert,Hsiao, Hsu-Ming,Chen, Tsai-Hsiu,Chu, Ming-Wen,Yang, Chia-Min

supporting information, p. 11939 - 11942 (2016/10/09)

A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.

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