937025-89-3

Basic information

• Product Name: cinnamyl pivaloyloxycarbamate
• Synonyms: cinnamyl pivaloyloxycarbamate
• CAS NO: 937025-89-3
• Molecular Weight: 277.32
• Mol File: 937025-89-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cinnamyl pivaloyloxycarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: cinnamyl pivaloyloxycarbamate(937025-89-3)
• EPA Substance Registry System: cinnamyl pivaloyloxycarbamate(937025-89-3)

Safety Data

• Hazardous Substances Data: 937025-89-3(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 3282-30-2 pivaloyl chloride 
• 103723-92-8 (E)-3-phenylprop-2-enyl N-hydroxycarbamate 

Downstream Products

• 1078-70-2 3-phenylprop-2-enyloxycarbonylamine 

Relevant articles and documents

Tethered aminohydroxylation: Dramatic improvements to the process

Changing the identity of the N leaving group on a hydroxylamine-based reoxidant gives a dramatic improvement to the tethered aminohydroxylation reaction. Using OCOC6F5 as a leaving group means that only 1 mol % of osmium is required and yields as high as 98% can be obtained. Acyclic homoallylic alcohols were substrates considered too unreactive for effective use in the tethered aminohydroxylation reaction; improved reaction conditions mean that they have now become viable substrates for oxidation.