947696-31-3

Basic information

• Product Name: [Ni(P(C₆H₁₁)3)(OS(C₆H₅)(O)NCH(C₆H₅)C₂(C₆H₅)2)]
• Synonyms: [Ni(P(C₆H₁₁)3)(OS(C₆H₅)(O)NCH(C₆H₅)C₂(C₆H₅)2)]
• CAS NO: 947696-31-3
• Molecular Weight: 762.659
• Mol File: 947696-31-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ni(P(C₆H₁₁)3)(OS(C₆H₅)(O)NCH(C₆H₅)C₂(C₆H₅)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(P(C₆H₁₁)3)(OS(C₆H₅)(O)NCH(C₆H₅)C₂(C₆H₅)2)](947696-31-3)
• EPA Substance Registry System: [Ni(P(C₆H₁₁)3)(OS(C₆H₅)(O)NCH(C₆H₅)C₂(C₆H₅)2)](947696-31-3)

Safety Data

• Hazardous Substances Data: 947696-31-3(Hazardous Substances Data)

Upstream product

• 947696-30-2 η2-C6H5CH(Ni(P(C6H11)3)2)NSO2C6H5 
• 501-65-5 diphenyl acetylene 
• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 13909-34-7 N-benzylidenephenylsulfonamide 
• 2622-14-2 tricyclohexylphosphine 

Downstream Products

• 947696-33-5 [Ni(P(C₆H₁₁)3)(N(SO₂C₆H₅)CH(C₆H₅)(CC₆H₅)4)] 
• 31554-20-8 3,4,5-triphenyl-1,5-dihydro-pyrrol-2-one 
• 1170036-10-8 (Al(CH₃)C₃H(C₆H₅)3NSO₂C₆H₅)2 
• 947696-34-6 [Ni(P(C₆H₁₁)3)(N(SO₂C₆H₅)CH(C₆H₅)(CC₆H₅)2(CCH₃)2)] 

Relevant articles and documents

Formation of an aza-nickelacycle by reaction of an imine and an alkyne with nickel(0): Oxidative cyclization, insertion, and reductive elimination

(Chemical Equation Presented) Cyclize, add, reduce: The oxidative cyclization of an imine and an alkyne with nickel(0) followed by the insertion of a second alkyne gives a seven-membered aza-nickelacycle (see scheme). Subsequent reductive elimination yiel