95046-15-4

Basic information

• Product Name: Benzene, 1-(1,2-hexadienyl)-4-methoxy-
• CAS NO: 95046-15-4
• Molecular Formula: C13H16O
• Molecular Weight: 188.269
• Mol File: 95046-15-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,2-hexadienyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,2-hexadienyl)-4-methoxy-(95046-15-4)
• EPA Substance Registry System: Benzene, 1-(1,2-hexadienyl)-4-methoxy-(95046-15-4)

Safety Data

• Hazardous Substances Data: 95046-15-4(Hazardous Substances Data)

Upstream product

• 95046-14-3 1-(p-methoxyphenyl)-1-(trimethylsilyl)-1,2-hexadiene 
• 123-11-5 4-methoxy-benzaldehyde 
• 627-19-0 1-Pentyne 
• 19350-72-2 N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide 
• 693-02-7 hex-1-yne 
• 556812-41-0 4-methoxy-2-(trimethylsilyl)phenyl triflate 
• 150-76-5 4-methoxy-phenol 
• 17332-11-5 2-bromo-4-methoxyphenol 
• 85630-29-1 4-methoxy-2-trimethylsilylphenol 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 17889-42-8 1-(trimethylsilyl)-1-hexyn-3-ol 

Downstream Products

• 134815-65-9 1-((1E,3E)-hexa-1,3-dienyl)-4-methoxybenzene 

Relevant articles and documents

Rhodium(III)-Catalyzed Directed C-H Dienylation of Anilides with Allenes Leads to Highly Conjugated Systems

Allenes are unique coupling partners in transition-metal-catalyzed C-H functionalization leading to a variety of products via alkenylation, allenylation, allylation, and annulation reactions. The outcome is governed by both the reactivity of the allene and the formation and stability of the organometallic intermediate. An efficient Rh(III)-catalyzed, weakly coordinating group-directed dienylation of electronically unbiased allenes is developed using an N-acyl amino acid as a ligand. Further elaboration of the dienylated products to construct polycyclic compounds is also described.

Synthesis of Allenes by Nickel-Catalyzed Grignard Reactions with Silylpropargyl Alcohols

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