95081-49-5Relevant articles and documents
Structure and Synthesis of Miyaginin, a p-Allylphenyl Glycoside from Lespedeza thunbergii forma macrantha
Ojika, Makoto,Kuyama, Hiroki,Niwa, Haruki,Yamada, Kiyoyuki
, p. 2893 - 2896 (1984)
The structure of miyaginin previously reported as p-vinylphenyl O-D-xylosyl-(1->6)-D-glucoside without stereochemical assignment of two glycosidic linkages was reinvestigated by spectral and chemical means and shown to be revised as p-allylphenyl O-β-D-xylopyranosyl-(1->6)-β-D-glucopyranoside (p-allylphenyl β-primeveroside).In order to confirm the revised structure, an unambiguous synthesis of miyaginin was performed.
