952-06-7

Basic information

• Product Name: DeoxyBenzoinOxime
• Synonyms: (1E)-1,2-Diphenylethanone Oxime;(E)-2-Phenylacetophenone Oxime;SC-66276;α-Phenylacetophenone oxime;Ethanone,1,2-diphenyl-, oxime;(1E)-1,2-diphenylethanone oxiMe (Parecoxib sodiuM inteMediate);2-Phenylacetophenone oxiMe;Benzyl phenyl ketoxime
• CAS NO: 952-06-7
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.25912
• EINECS: 206-641-4
• Product Categories: Aromatics
• Mol File: 952-06-7.mol
• Article Data: 60

Chemical Properties

• Melting Point: 98℃
• Boiling Point: 375.4°Cat760mmHg
• Flash Point: 238°C
• Appearance: /
• Density: 1.04±0.1 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 2.65E-06mmHg at 25°C
• Refractive Index: 1.562
• PKA: 11.07±0.11(Predicted)
• CAS DataBase Reference: DeoxyBenzoinOxime(CAS DataBase Reference)
• NIST Chemistry Reference: DeoxyBenzoinOxime(952-06-7)
• EPA Substance Registry System: DeoxyBenzoinOxime(952-06-7)

Safety Data

• Hazardous Substances Data: 952-06-7(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C14H13NO/c16-15-14(13-9-5-2-6-10-13)11-12-7-3-1-4-8-12/h1-10,16H,11H2/b15-14+

Upstream product

• 3442-15-7 1,4-diphenylbutane-1,3-dione 
• 67-56-1 methanol 
• 5468-44-0 α-nitrostyrene 
• 71-43-2 benzene 
• 3638-64-0 1-nitroethylene 
• 31247-21-9 2,3-diphenylthiirene 1-oxide 
• 140-29-4 phenylacetonitrile 
• 98-80-6 phenylboronic acid 
• 451-40-1 phenyl benzyl ketone 
• 546-88-3 acetylhydroxamic acid 
• 588-59-0 stilbene 
• 501-65-5 diphenyl acetylene 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 60-29-7 diethyl ether 

Downstream Products

• 10265-81-3 2-benzyl-3,4-diphenylquinoline 
• 19690-01-8 1,2-diphenylethanone O-acetyl oxime 

Relevant articles and documents

AgNO3as Nitrogen Source for Cu-Catalyzed Cyclization of Oximes with Isocyanates: A Facile Route to N-2-Aryl-1,2,3-triazoles

A versatile copper-catalyzed [3 + 1 + 1] annulation of oximes and isocyanates with AgNO3 is described. In this conversion, AgNO3 and isocyanates instead of conventional azide or diazonium reagents were used as the nitrogen source. This three-component transformation was achieved by cleaving N-O/C-H/C-N bonds and building CN/N-N bonds, which provides a strategy to prepare N-2-aryl-1,2,3-triazoles with a good substrate and functional compatibility.

Copper-Catalyzed Three-Component Carboboronation of Allenes Using Highly Strained Cyclic Ketimines as Electrophiles

A diastereoselective copper and NHC-ligand-catalyzed three-component difunctionalization of allenes with bis(pinacolato)diboron and 2H-azirines to afford borylated allylaziridines is described. The reaction exhibits complete diastereoselectivity and good yields, and the further chlorination of the corresponding borylated products was also performed. It is believed that the high ring-strain force of 2H-azirines facilitates the reaction. More chemical transformations of borylated allylaziridines are also reported.

Zinc-Enabled Annulation of Trifluorodiazoethane with 2 H-Azirines to Construct Trifluoromethyl Pyrazolines, Pyrazoles, and Pyridazines

A diethylzinc-promoted unconventional annulation reaction of 2,2,2-trifluorodiazoethane with 2H-azirines is described. This transformation involves two [3 + 2] cycloaddition steps and one dinitrogen extrusion process in one pot, thus giving a broad array