953-21-9

Basic information

• Product Name: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline
• CAS NO: 953-21-9
• Molecular Formula: C₁₅H₁₃N
• Molecular Weight: 207.2704
• Mol File: 953-21-9.mol
• Article Data: 108

Chemical Properties

• Boiling Point: 350.5°C at 760 mmHg
• Flash Point: 158°C
• Density: 0.93g/cm³
• Vapor Pressure: 8.87E-05mmHg at 25°C
• Refractive Index: 1.54
• CAS DataBase Reference: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(953-21-9)
• EPA Substance Registry System: N-[(1E)-3-phenylprop-2-en-1-ylidene]aniline(953-21-9)

Safety Data

• Hazardous Substances Data: 953-21-9(Hazardous Substances Data)

Upstream product

• 104-55-2 3-phenyl-propenal 
• 622-37-7 Phenyl azide 
• 62-53-3 aniline 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 103-49-1 dibenzylamine 
• 100-46-9 benzylamine 
• 109-89-7 diethylamine 
• 14371-10-9 (E)-3-phenylpropenal 
• 92573-86-9 N-[(2E)-3-phenylprop-2-en-1-yl]aniline 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 98-95-3 nitrobenzene 
• 118714-23-1 cinnamylideneaniline hydrochloride 
• 118714-25-3 N-(p-methylcinnamylidene)-p-toluidine hydrochloride 
• 17408-56-9 3-anilino-5-phenyl-5H-furan-2-one 

Downstream Products

• 53646-86-9 1,2,3-triphenyl-1H-pyrrole 
• 139696-66-5 1,3-diphenyl-2-methoxy-2-methyl-1,2-azasiloline-4 
• 158172-41-9 1,5-diphenyl-2-methoxy-2-methyl-1,2-azasiloline-3 
• 117063-47-5 bis(cinnamylideneaniline)chlorocopper(I) 
• 1159386-70-5 N-(2-methylene-1-styrylbut-3-en-1-yl)phenylamine 
• 147688-81-1 N,4-Diphenyl-2-cyano-1-azabutadiene 
• 69139-24-8 (Z)-4-((E)-3-phenylallylidene)isochromane-1,3-dione 

Relevant articles and documents

Cobalt-Catalyzed Deoxygenative Hydroboration of Nitro Compounds and Applications to One-Pot Synthesis of Aldimines and Amides

The commercially available and bench-stable Co(acac)2 ligated with bis[(2-diphenylphosphino)phenyl] ether (dpephos) was employed for selective room temperature hydroboration of nitro compounds with HBPin (TOF up to 4615 h?1), tolerating halide, hydroxy, amino, ether, ester, lactone, amide and heteroaromatic functionalities. These reactions offered a direct access to a variety of N-borylamines RN(H)BPin, which were in situ treated with aldehydes and carboxylic acids to produce a series of aldimines and secondary carboxamides without the need for dehydrating and/or coupling reagents. Combination of these transformations in a sequential one-pot manner allowed for direct and selective synthesis of aldimines and secondary carboxamides from readily available and inexpensive nitro compounds.

Sulfated polyborate: A dual catalyst for the reductive amination of aldehydes and ketones by NaBH4

An efficient, quick, and environment-friendly one-pot reductive amination of aldehydes or ketones was developed. In ethanol at 70 °C, a imination catalyzed by sulfated polyborate and further reduced by sodium borohydride yields various amines. The present method has many significant benefits, including a shorter reaction time, excellent yields, and a hassle-free, straightforward experimental process. The reaction has a wide range of applications due to its flexibility, including secondary amine for reductive amination.

Ex-vivo antimalarial and in-vitro biological activities of newly synthesized co(ii) complex with schiff base

The first-row transition metal complex of Schiff base has been synthesized and characterized based on physicochemical spectral and biochemical methods. The metal-ligand stoichiometry and molecular formula of the complex assessed by Elemental analysis and