95391-85-8

Basic information

• Product Name: Benzene, [[2-(phenylseleno)ethenyl]thio]-, (E)-
• CAS NO: 95391-85-8
• Molecular Formula: C14H12SSe
• Molecular Weight: 291.275
• Mol File: 95391-85-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [[2-(phenylseleno)ethenyl]thio]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[2-(phenylseleno)ethenyl]thio]-, (E)-(95391-85-8)
• EPA Substance Registry System: Benzene, [[2-(phenylseleno)ethenyl]thio]-, (E)-(95391-85-8)

Safety Data

• Hazardous Substances Data: 95391-85-8(Hazardous Substances Data)

Upstream product

• 13296-07-6 2-(phenylseleno)-1-bromoethylene 
• 930-69-8 sodium thiophenolate 
• 931-59-9 benzenesulfenyl chloride 
• 65910-12-5 (phenylselanyl)acetylene 
• 26620-11-1 (E)-2-chlorovinylthiobenzene 
• 23974-72-3 sodium phenylselenide 

Downstream Products

• 52071-98-4 (E)-1-phenylsulfanyl-3-methoxypropene 

Relevant articles and documents

A facile stereoselective synthesis of (E)-1-arylseleno-2- arylsulfanylethenes via hydrozirconation of arylselenoethynes

Hydrozirconation of arylselenoethynes 1 gave (E)-2- arylselenovinylzirconium(IV) complexes 2, which reacted with arylsulfenyl chlorides 3 stereoselectively to afford (E)-1-arylseleno-2-arylsulfanylethenes 4 in good yields. (E)-1-Arylseleno-2-arylsulfanyle

NEW SYNTHESIS OF VINYL SELENIDES NUCLEOPHILIC SUBSTITUTIONS OF UNACTIVATED VINYL HALIDES BY SELENIDE ANIONS

Alkyl and aryl selenide anions react with unactivated vinyl halides, in dipolar aprotic solvents, to give alkyl or aryl vinyl selenides in good yields.These reactions are stereospecific and occur with retention of configuration.