95599-69-2

Basic information

• Product Name: Silanediol, bis(2,4,6-trimethylphenyl)-
• CAS NO: 95599-69-2
• Molecular Formula: C18H24O2Si
• Molecular Weight: 300.473
• Mol File: 95599-69-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silanediol, bis(2,4,6-trimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanediol, bis(2,4,6-trimethylphenyl)-(95599-69-2)
• EPA Substance Registry System: Silanediol, bis(2,4,6-trimethylphenyl)-(95599-69-2)

Safety Data

• Hazardous Substances Data: 95599-69-2(Hazardous Substances Data)

Upstream product

• 2633-66-1 2-mesitylmagnesium bromide 
• 120578-34-9 (2,4,6-trimethylphenyl)silane 
• 99798-82-0 bis(2,4,6-trimethyphenyl)silane 
• 80785-72-4 tetramesityldisilene 
• 85656-15-1 C₃₁H₃₈OSi 
• 160011-53-0 1,1-dimesitylneopentylsilene 
• 160011-52-9 dimesitylvinylfluorosilane 
• 119106-07-9 dimesitylfluorosilane 
• 50490-74-9 chloro-di-(2,4,6-trimethylphenyl)silane 
• 576-83-0 2,4,6-trimethylphenyl bromide 

Downstream Products

• 1582790-19-9 C₇H₆N₂*C₁₈H₂₄O₂Si 

Relevant articles and documents

Silanediol hydrogen bonding activation of carbonyl compounds

Geo-inspired activation: The first example of silanediols activating amide and aldehyde substrates through hydrogen bonding is described. Both NMR and X-ray co-crystallization studies demonstrate binding modes and affinity, and show that silanediol hydrogen-bonding assemblies can be modulated by the addition of carbonyl compounds. These silanols show catalysis in a Diels-Alder reaction and provide insight into the design of new organocatalysts (see figure). Copyright

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The dimesitylneopentylsilene Mes2Si=CH-CH2tBu 1 is obtained in almost quantitative yield by reaction of tert-butyllithium with dimesitylvinylfluorosilane 4; 1 is certainly one of the most easily available stable silenes. In spite of its stability, 1 presents a high reactivity in the field of classical chemistry of organometallic alkenes such as addition or cycloaddition reactions and, in some cases, an original behaviour of ene-reagent (towards benzaldehyde) and both ene- and enophilic-reagent (towards acetophenone).