958878-64-3Relevant articles and documents
Selective defluorination approach to N-Cbz-3,3-difluoro-2- difluoromethylenepyrrolidine and its application to 3,3-difluoroproline dipeptide synthesis
Guo, Yong,Fujiwara, Kana,Amii, Hideki,Uneyama, Kenji
, p. 8523 - 8526 (2007)
(Chemical Equation Presented) Mg-promoted defluorination of N-(p-methoxyphenyl)bis-(trifluoromethyl)imine 1 gave perfluoroenamine 2, which was readily transformed to N-Cbz-2-trifluoromethyl-3,3-difluoropyrrolidine 10. Chemoselective defluorination from th