96025-22-8

Basic information

• Product Name: Benzene, (5-methyl-3-hexenyl)-, (Z)-
• CAS NO: 96025-22-8
• Molecular Formula: C13H18
• Molecular Weight: 174.286
• Mol File: 96025-22-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, (5-methyl-3-hexenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (5-methyl-3-hexenyl)-, (Z)-(96025-22-8)
• EPA Substance Registry System: Benzene, (5-methyl-3-hexenyl)-, (Z)-(96025-22-8)

Safety Data

• Hazardous Substances Data: 96025-22-8(Hazardous Substances Data)

Upstream product

• 96025-20-6 (3R,4S)-3-Isopropyl-4-phenethyl-oxetan-2-one 
• 852178-76-8 5-(2-methylpropane-1-sulfonyl)-1-phenyl-1H-tetrazole 
• 104-53-0 3-phenyl-propionaldehyde 
• 95679-68-8 (5S,6R)-5-Isopropyl-6-phenethyl-[1,3]oxathian-4-one 
• 96025-18-2 3-Hydroxy-2-isopropyl-5-phenyl-pentanoic acid 
• 22884-29-3 isobutyltriphenylphosphonium bromide 

Relevant articles and documents

Molybdenum-Catalyzed Stereospecific Deoxygenation of Epoxides to Alkenes

Mild and simple catalytic systems consisting of molybdenum(VI) dichloride dioxide [MoO2Cl2] as a catalyst and a phosphine as reductant have been developed for the stereospecific deoxygenation of epoxides to alkenes. The reactions using 1,2-bis(diphenylphosphino)ethane (dppe) and triphenylphosphine (PPh3) proceed with retention and inversion of stereochemistry, respectively. The mild reaction tolerates the presence of various functional groups and affords stereodefined substituted olefins in good yields. (Figure presented.).

Simple protocol for enhanced (E)-selectivity in Julia-Kocienski reaction

A short and efficient Julia-Kocienski olefination protocol, based upon the use of chelating agents (18-crown-6 or TDA-1 for K+; 12-crown-4 or HMPA for Li+), was developed. This protocol enhances the (E)-selectivity of the reaction an

THREO SELECTIVE CROSS ALDOL CONDENSATION WITH THIOAMIDE ENOLATES GENERATED BY A MICHAEL ADDITION OF ORGANOMETALLICS TO UNSATURATED THIOAMIDES

Crotonthioamide, sorbothioamide, and cinnamothioamide undergo a threo selective aldol condensation via their enolates generated by a Michael addition of organometallics.