97253-74-2Relevant articles and documents
Stannic chloride-induced unsymmetrical C-se bond cleavage of bis(N,N-dimethylcarbamoylseleno)methanes: Novel generation of selenoaldehydes
Gong, Yaling,Shimada, Kazuaki,Nakamura, Hidenori,Fujiyama, Masamichi,Kodama, Akihiro,Otsuki, Miyuki,Matsumoto, Rei,Aoyagi, Shigenobu,Takikawa, Yuji
, p. 125 - 135 (2006)
Treatment of bis(N,N-dimethylcarbamoylseleno)methanes with SnCl4 afforded β-1,3,5-triselenanes in moderate to high yields, and the key intermediates of the reactions, i.e., acylselonium ions and selenoaldehydes, were successfully trapped by usi
Palladium-catalyzed conversion of benzylic and allylic halides into α-aryl and β,γ-unsaturated tertiary amides by the use of a carbamoylsilane
Cunico, Robert F.,Pandey, Rajesh K.
, p. 9048 - 9050 (2007/10/03)
Treatment of allylic and benzylic halides with N,N- dimethylcarbamoyl(trimethyl)silane in the presence of tetrakis- (triphenylphosphine)palladium(0) affords tertiary amides, which arise from the replacement of the halogen by the N,N-dimethylcarbamoyl group.