97427-59-3

Basic information

• Product Name: dimethyl 2-benzoylcyclopropane-1,1-dicarboxylate
• Synonyms: dimethyl 2-benzoylcyclopropane-1,1-dicarboxylate
• CAS NO: 97427-59-3
• Molecular Weight: 262.262
• Mol File: 97427-59-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dimethyl 2-benzoylcyclopropane-1,1-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-benzoylcyclopropane-1,1-dicarboxylate(97427-59-3)
• EPA Substance Registry System: dimethyl 2-benzoylcyclopropane-1,1-dicarboxylate(97427-59-3)

Safety Data

• Hazardous Substances Data: 97427-59-3(Hazardous Substances Data)

Upstream product

• 97427-62-8 4,4-bismethoxycarbonyl-1-oxo-1-phenylbutane 
• 97427-58-2 methyl 4-bromo-5-oxo-2-bis(methoxycarbonyl)-5-phenylpentanoate 
• 90484-46-1 2-bromo-1-phenylprop-2-en-1-one 
• 108-59-8 malonic acid dimethyl ester 
• 879-72-1 3-(dimethylamino)propiophenone hydrochloride 
• 768-03-6 Phenyl vinyl ketone 
• 29636-75-7 3-bromo-1-phenylpropan-1-one 
• 71-43-2 benzene 
• 936-59-4 3-chloropropiophenone 

Downstream Products

• 6366-29-6 2-benzoyl-cyclopropane-1,1-dicarboxylic acid 
• 1601-82-7 (+/-)-trans-2-benzoyl-cyclopropane-carboxylic acid-⁽¹⁾ 
• 1601-81-6 cis 2-benzoylcyclopropanecarboxylic acid 

Relevant articles and documents

Anodic cyclization of dimethyl 2-(3-Oxo-3-arylpropyl) malonates into the corresponding dimethyl 2-aroylcyclopropane-1,1-dicarboxylates

A variety of dimethyl 2-(3-oxo-3-arylpropyl)malonates were electrooxidized in methanol, in the presence of potassium iodide and a base or a neutral salt, to give the corresponding cyclized dimethyl 2-aroylcyclopropane-1,1- dicarboxylates in moderate to good yields. The reactions were carried out under extremely mild reaction conditions, in which the optimal amount of electrolytic current varied from 2.12-2.41 F·mol-1 depending on the substrates. The reaction presumably proceeds via a two-electron oxidation process, in which iodide ions play an important role as the electron carrier between the anode and the substrate. Georg Thieme Verlag Stuttgart. New York.