98018-66-7

Basic information

• Product Name: N-Benzyl-N-(2-chlorophenyl)amine
• Synonyms: N-Benzyl-N-(2-chlorophenyl)amine;Benzenemethanamine, N-(2-chlorophenyl)-;Benzyl-(2-chloro-phenyl)-amine
• CAS NO: 98018-66-7
• Molecular Formula: C₁₃H₁₂ClN
• Molecular Weight: 217.69408
• Mol File: 98018-66-7.mol
• Article Data: 65

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Benzyl-N-(2-chlorophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzyl-N-(2-chlorophenyl)amine(98018-66-7)
• EPA Substance Registry System: N-Benzyl-N-(2-chlorophenyl)amine(98018-66-7)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 98018-66-7(Hazardous Substances Data)

Usage

General Description

N-Benzyl-N-(2-chlorophenyl)amine is an organic chemical compound that belongs to the class of amines. It is a white to off-white crystalline solid that is commonly used in the synthesis of various pharmaceuticals and agrochemicals. N-Benzyl-N-(2-chlorophenyl)amine is also utilized as a building block in the manufacturing of dyes, pigments, and other organic compounds. N-Benzyl-N-(2-chlorophenyl)amine is known for its strong odor and is considered hazardous if ingested, inhaled, or comes into contact with skin or eyes. It is important to handle this compound with caution and use appropriate protective equipment when working with it.

Upstream product

• 100-44-7 benzyl chloride 
• 95-51-2 o-chloroaniline 
• 100-39-0 benzyl bromide 
• 95-57-8 2-monochlorophenol 
• 79-04-9 chloroacetyl chloride 
• 100-46-9 benzylamine 
• 615-41-8 2-iodochlorobenzene 
• 857796-41-9 N-benzyl-N-(2-chlorophenyl)hydrazine 
• 10449-07-7 (2-chlorophenyl)hydrazine 
• 98-88-4 benzoyl chloride 
• 873-76-7 para-Chlorobenzyl alcohol 
• 108-88-3 toluene 
• 88-73-3 2-Chloronitrobenzene 
• 100-51-6 benzyl alcohol 

Downstream Products

• 74480-64-1 N-Benzyl-N-(2-chloro-phenyl)-2-methyl-acrylamide 
• 229-87-8 phenanthridine 
• 758640-21-0 N-Benzylaniline 
• 776-35-2 9,10-dihydrophenanthrene 
• 50844-93-4 5,6,5',6'-tetrahydro-[6,6']biphenanthridinyl 
• 52604-15-6 1-benzyl-2-phenyl-1H-indole 
• 114081-14-0 1-benzyl-3,3-dimethyl-1,3-dihydro-indol-2-one 
• 95-51-2 o-chloroaniline 
• 108-88-3 toluene 
• 17901-58-5 1-benzyl-2-methyl-1H-indole 
• 1290612-63-3 benzyl{3-[benzyl(2-chlorophenyl)amino]-1Hisoindol-1-ylidene}(2-chlorophenyl)ammonium perchlorate 
• 1164334-42-2 N-benzyl-N-(2-chlorophenyl)-2-phenylbutanamide 
• 1164334-53-5 N-benzyl-N-(2-bromophenyl)-2-(naphthalen-1-yl)propanamide 
• 1164334-58-0 N-benzyl-N-(2-chlorophenyl)-2-(2-methoxyphenyl)-3-phenyl-propionamide 

Relevant articles and documents

Selective C-C bonds formation, N-alkylation and benzo[d]imidazoles synthesis by a recyclable zinc composite

Earth abundant metals are much less expensive, promising, valuable metals and could be served as catalysts for the borrowing hydrogen reaction, dehydrogenation and heterocycles synthesis, instead of noble metals. The uniformly dispersed zinc composites were designed, synthesized and carefully characterized by means of XPS, EDS, TEM and XRD. The resulting zinc composite showed good catalytic activity for the N-alkylation of amines with amines, ketones with alcohols in water under base-free conditions, while unsaturated carbonyl compounds could also be synthesized by tuning the reaction conditions. Importantly, it was the first time to realize the synthesis of 2-aryl-1H-benzo[d]imidazole derivatives by using this zinc composite under green conditions. Meanwhile, this zinc catalyst could be easily recovered and reused for at least five times.

Iron-Catalyzed Oxidative Amination of Benzylic C(sp3)–H Bonds with Anilines

Iron-catalyzed oxidative amination of benzylic C(sp3)–H bonds with anilines bearing electron-withdrawing groups (EWGs) or electron-donating groups (EDGs) is realized based on simple variations of N-substituents on imidazolium cations in novel ionic Fe(III) complexes. The structural modification of the imidazolium cation resulted in regulation of the redox potential and the catalytic performance of the iron metal center. Using DTBP as oxidant, [HItBu][FeBr4] showed the highest catalytic activity for anilines bearing EWGs, while [HIPym][FeBr4] was more efficient for EDG-substituted anilines. This work provides alternative access to benzylamines with the advantages of both a wide substrate scope and iron catalysis.

Photocatalytic one-pot multidirectional N-alkylation over Pt/D-TiO2/Ti3C2: Ti3C2-based short-range directional charge transmission

Visible-light-induced one-pot, multistep, and chemoselectivity adjustable reactions highlight the economical, sustainable, and green process. Herein, we report Pt nanoparticles dispersed on S and N co-doped titanium dioxide/titanium carbide (MXene) (3%Pt/