98147-48-9

Basic information

• Product Name: 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
• Synonyms: 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
• CAS NO: 98147-48-9
• Molecular Weight: 294.458
• Mol File: 98147-48-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate(98147-48-9)
• EPA Substance Registry System: 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate(98147-48-9)

Safety Data

• Hazardous Substances Data: 98147-48-9(Hazardous Substances Data)

Upstream product

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 2216-51-5 (-)-menthol 
• 89-78-1 menthol 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 19158-51-1 P-toluenesulfonyl cyanide 
• 100-51-6 benzyl alcohol 
• 15356-70-4 menthol 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 103-19-5 di(p-tolyl) disulfide 
• 6481-73-8 S-p-tolyl 4-methylbenzenesulfinothioate 

Downstream Products

• 2216-51-5 (-)-menthol 
• 110258-89-4 (-)-(R)-p-tolylsulfinyl-5 hydroxymethyl-4 pentene-4(E) yne-2 ol-1 
• 110258-86-1 (-)-(R)-p-tolylsulfinyl-1 pentyl-2 nonene-1(Z) yne-3 
• 110258-85-0 (-)-(R)-p-tolylsulfinyl-1 methyl-2 pentene-1(Z) yne-3 
• 58059-08-8 tert-butyl (R)-p-toluenesulfinylacetate 
• 110258-90-7 (-)-(R)₂-p-toluenesulfinyl-1 (hydroxy-1 hexyl)-2 decene-1(E) yne-3 ol-5 
• 1432487-20-1 2-bromo-5-fluoro-1-(p-tolylsulfinyl)benzene 
• 1432487-19-8 2-bromo-4-fluoro-1-(p-tolylsulfinyl)benzene 
• 1432487-18-7 2-bromo-4-chloro-1-(p-tolylsulfinyl)benzene 
• 135145-16-3 (+/-)-2-bromophenyl 4-methylphenyl sulfoxide 

Relevant articles and documents

Sodium Arenesulfinates-Involved Sulfinate Synthesis Revisited: Improved Synthesis and Revised Reaction Mechanism

Reaction of alcohols with sodium arenesulfinates could afford either sulfones or sulfinates, and O-attack of sulfinate anions onto the in situ generated carbocation intermediates from alcohols was the previous proposed reaction mechanism in many syntheses of sulfinates. This concept, which is often used consciously or unconsciously, was revised herein by using isotopic labeling experiments and development of an improved sulfinate synthesis. The improved sulfinate synthetic protocol possesses many advantages such as a high sulfinate/sulfone selectivity, a broad substrate scope, metal-free, and mild reaction conditions. The revised reaction mechanism necessitates revision of many previous proposed reaction mechanisms in literatures.

Highly diastereoselective synthesis and easy method for synthesis of optically active sulfinate esters from aromatic disulfides

One-step synthesis of chiral aromatic sulfinate esters 2 from aromatic disulfides 1 using lead tetraacetate is reported. The yields are good to excellent and diastereoselectivity is high.

O-sulfinylation with methanesulfonyl cyanide or p-toluenesulfonyl cyanide and DBU

Reaction of methanesulfonyl cyanide or p-toluenesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates is suggested.