99018-39-0Relevant articles and documents
Investigation of a Model for 1,2-Asymmetric Induction in Reactions of α-Carbalkoxy Radicals: A Stereochemical Comparison of Reactions of α-Carbalkoxy Radicals and Ester Enolates
Hart, David J.,Krishnamurthy, Ramanarayanan
, p. 4457 - 4470 (2007/10/02)
The stereochemical course of reductions and allylations of α-carbalkoxy radicals with chiral centers at the β-position are reported.Radicals without polar substituents, with alkoxyl or acetoxyl groups, and with hydroxyl groups at the β-position were exami