993-13-5Relevant articles and documents
Nichol et al.
, p. 1008,1010 (1967)
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Thompson
, p. 3292 (1952)
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A Peanut-Like Sb-Embedded Polyoxoniobate Cage for Hydrolytic Decomposition of Chemical Warfare Agent
Wu, Yan-Lan,Zhong, Zhuo-Hao,Wu, Ping-Xin,Sun, Yan-Qiong,Li, Xin-Xiong,Zheng, Shou-Tian
, p. 1505 - 1509 (2021)
A Sb-embedded polyoxoniobate has been originally synthesized under hydrothermal conditions. Particularly, the peanut-like [Sb2Nb24O72]18? cluster cage in 1 with C2h symmetry is composed of two 9-nuclear {SbNb9O33} motifs and one {Nb6O24} crown-shaped ring. The compound 1 present the novel structure of Sb-substituted sandwich-type polyoxoniobate with antimoniobate cluster cage. Decomposition catalytic studies indicate that compound 1 exhibits good hydrolytic activity and stability on the degradation of nerve agent simulant dimethylphosphonate (DMMP).
Mass Spectrometric Identification of Methylphosphonic Acid: The Hydrolysis Product of Isopropyl Methylphosphonofluoridate and Pinacolyl Methylphosphonofluoridate
Tripathi, Durgesh N.,Pandey, Karuna S.,Bhattacharya, Arabinda,Vaidyanathaswamy, Ramamoorthy
, p. 823 - 824 (1992)
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Magnesium Exchanged Zirconium Metal-Organic Frameworks with Improved Detoxification Properties of Nerve Agents
Gil-San-Millan, Rodrigo,López-Maya, Elena,Platero-Prats, Ana E.,Torres-Pérez, Virginia,Delgado, Pedro,Augustyniak, Adam W.,Kim, Min Kun,Lee, Hae Wan,Ryu, Sam Gon,Navarro, Jorge A. R.
supporting information, p. 11801 - 11805 (2019/08/28)
UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.
Investigating the breakdown of the nerve agent simulant methyl paraoxon and chemical warfare agents GB and VX using nitrogen containing bases
Wilson, Craig,Cooper, Nicholas J.,Briggs, Michael E.,Cooper, Andrew I.,Adams, Dave J.
supporting information, p. 9285 - 9291 (2019/01/03)
A range of nitrogen containing bases was tested for the hydrolysis of a nerve agent simulant, methyl paraoxon (MP), and the chemical warfare agents, GB and VX. The product distribution was found to be highly dependant on the basicity of the base and the quantity of water used for the hydrolysis. This study is important in the design of decontamination technology, which often involve mimics of CWAs.