Orientation of the isopropyl grouping in Isopropyl chloroformate (cas 108-23-6) and isopropyl cyanoformate
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Add time:08/19/2019 Source:sciencedirect.com
The vapour phase infrared contours of the carbonyl stretching of five differently deuterated derivatives of Isopropyl chloroformate (cas 108-23-6), and of three differently deuterated derivatives of isopropyl cyanoformate have been investigated. Simulations using rigid asymmetric top calculations of the observed contours indicate that the COCH dihedral angle is close to 20° in both the chloroformate and the cyanoformate ester.
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