A new easily accessible chiral phosphite–phosphoramidite ligand based on 2-Anilinoethanol (cas 122-98-5) and R-BINOL moieties for Rh-catalyzed asymmetric olefin hydrogenation
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Add time:09/07/2019 Source:sciencedirect.com
A novel chiral phosphite–phosphoramidite ligand based on 2-Anilinoethanol (cas 122-98-5) and R-BINOL moieties has been synthesized in one-pot. The ligand was evaluated in the rhodium-catalyzed enantioselective hydrogenation of α- and β-dehydroamino acid derivatives and dimethyl itaconate in three different solvents at 25 °C, at 1 or 50 bar of hydrogen pressure. The solvent and the pressure effect are discussed.
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