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(-)-Camphor

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(-)-Camphor

EINECS 207-354-7
CAS No. 464-48-2 Density 0.982 g/cm3
PSA 17.07000 LogP 2.40170
Solubility Soluble in water. (0.34 g/L) at 20°C Melting Point 177-179 °C(lit.)
Formula C10H16O Boiling Point 207.4 °C at 760 mmHg
Molecular Weight 152.236 Flash Point 64.4 °C
Transport Information UN 2717 Appearance white crystals
Safety 16-26 Risk Codes 11-36/37/38
Molecular Structure Molecular Structure of 464-48-2 ((-)-Camphor) Hazard Symbols IrritantXi, FlammableF
Synonyms

Bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-, (1S)-;Camphor, (1S,4S)-(-)- (8CI);(-)-Alcanfor;(-)-Camphor;(1S)-(-)-Camphor;(1S)-Camphor;(1S,4S)-(-)-Camphor;(S)-(-)-Camphor;NSC 26351;

Article Data 126

(-)-Camphor Chemical Properties

Molecule structure of l-Camphor (CAS NO.464-48-2):


Molecular Formula: C10H16O
Molecular Weight: 152.23 g/mol
Melting Point: 177-179 °C(lit.)
Boiling point: 207.4 °C at 760 mmHg
Flash Point: 64.4 °C
Density: 0.982 g/cm3
Vapor density: 5.24 (vs air)
Refractive index: -44 ° (C=20, EtOH)
Surface Tension: 31.5 dyne/cm
Enthalpy of Vaporization: 44.37 kJ/mol
Vapour Pressure: 0.225 mmHg at 25 °C
XLogP3-AA: 2.2
H-Bond Acceptor: 1
Canonical SMILES: CC1(C2CCC1(C(=O)C2)C)C
Isomeric SMILES: C[C@]12CC[C@H](C1(C)C)CC2=O
InChI: InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
InChIKey: DSSYKIVIOFKYAU-OIBJUYFYSA-N
EINECS: 207-354-7
Product Categories: Miscellaneous Natural Products; Bicyclic Monoterpenes; Biochemistry; Camphor, etc. (Plasticizer); Functional Materials; Plasticizer; Terpenes

(-)-Camphor Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 320mg/kg (320mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02534,
rat LDLo oral 800ug/kg (0.8mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Journal of Pharmacology and Experimental Therapeutics. Vol. 1, Pg. 445, 1909.

(-)-Camphor Consensus Reports

Reported in EPA TSCA Inventory.

(-)-Camphor Safety Profile

Hazard Codes: FlammableF, IrritantXi
Risk Statements: 11-36/37/38 
R11:Highly flammable. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 2717 4.1/PG 3
WGK Germany: 1
RTECS: EX1250000
HazardClass: 4.1
PackingGroup: III
Deadly poison by ingestion. Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes. See also (IR,4 R)-(+)-CAMPHOR and CAMPHOR.

(-)-Camphor Specification

 l-Camphor (CAS NO.464-48-2) is also named as Alcanfor ; (1s,4s)-(-)-Campho ; 7,7-Trimethyl-(1s)-bicyclo(2.2.1)heptan-2-on ; 7,7-Trimethyl-(1s)-bicyclo[2.2.1]heptan-2-on ; Camphor, (1s,4s)-(-)- ; Camphor, l-, (-)- ; Camphore ; Levo-(-)-camphor . l-Camphor (CAS NO.464-48-2) is white crystals with slightly bitter and cooling taste. Burns with a bright, smoky flame. It is flammable. It is slightly water soluble. l-Camphor may be sensitive to heat and direct sunlight. It is incompatible with strong oxidizing agents, strong reducing agents and chlorinated solvents. Also incompatible with potassium permanganate. Salts of any kind should not be added to l-Camphor in water. Reacts violently with chromic anhydride .

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