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Cas Database |
| Name |
(R)-(-)-1-METHOXY-2-PROPANOL |
EINECS | 628-460-3 |
| CAS No. | 4984-22-9 | Density | 0.912 g/cm3 |
| PSA | 29.46000 | LogP | 0.01360 |
| Solubility | N/A | Melting Point |
-97 °C |
| Formula | C4H10O2 | Boiling Point | 118.5 °C at 760 mmHg |
| Molecular Weight | 90.1222 | Flash Point | 33.9 °C |
| Transport Information | UN 3092 3/PG 3 | Appearance | Colorless to light yellow liquid |
| Safety | 24-43-7/8 | Risk Codes | 10-15 |
| Molecular Structure |
|
Hazard Symbols |
 F,  Xn
|
| Synonyms |
2-Propanol,1-methoxy-, (R)-;2-Propanol, 1-methoxy-, D-(-)- (8CI);(-)-1-Methoxy-2-propanol;(R)-(-)-1-Methoxy-2-propanol; |
Article Data | 14 |
(R)-(-)-1-METHOXY-2-PROPANOL Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| In methanol for 13.5h; Reflux; | 86.51% |
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide at 35 - 65℃; for 16h; | 86.51% |
- 67-56-1
methanol
- 15448-47-2
(R)-propylene oxide
A
- 4984-22-9
(R)-1-methoxy-2-propanol
B
- 1589-47-5
2-methoxypropanol
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide for 5h; Reflux; | A 79% B n/a |
- 67-56-1
methanol
- 16088-62-3
(S)-Propylene oxide
A
- 4984-22-9
(R)-1-methoxy-2-propanol
B
- 6131-59-5
(2R)-2-methoxypropan-1-ol
C
- 19141-39-0
(R)-(-)-1-chloro-2-propanol
Conditions
| Conditions | Yield |
|---|---|
| With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 25℃; | A 52% B 42% C 6% |
Conditions
| Conditions | Yield |
|---|---|
| With methanol |
A
- 26550-55-0
(S)-1-Methoxy-propan-2-ol
B
- 4984-22-9
(R)-1-methoxy-2-propanol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogenchloride In tetrahydrofuran for 24h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
- 67-56-1
methanol
- 15448-47-2
(R)-propylene oxide
A
- 26550-55-0
(S)-1-Methoxy-propan-2-ol
B
- 4984-22-9
(R)-1-methoxy-2-propanol
C
- 116422-39-0
(S)-(+)-2-methoxypropanol
D
- 6131-59-5
(2R)-2-methoxypropan-1-ol
E
- 76946-23-1
(S)-(+)-1,2-dimethoxypropane
F
- 76946-22-0
(R)-(-)-1,2-dimethoxypropane
Conditions
| Conditions | Yield |
|---|---|
| With Methyl fluoride at 25℃; under 720 Torr; Product distribution; Mechanism; Irradiation; also in the presence of H2O or CH4; |
...Expand
- 67-56-1
methanol
- 16088-62-3
(S)-Propylene oxide
A
- 26550-55-0
(S)-1-Methoxy-propan-2-ol
B
- 4984-22-9
(R)-1-methoxy-2-propanol
C
- 116422-39-0
(S)-(+)-2-methoxypropanol
D
- 6131-59-5
(2R)-2-methoxypropan-1-ol
E
- 76946-23-1
(S)-(+)-1,2-dimethoxypropane
F
- 76946-22-0
(R)-(-)-1,2-dimethoxypropane
Conditions
| Conditions | Yield |
|---|---|
| With Methyl fluoride at 25℃; under 720 Torr; Product distribution; Mechanism; Irradiation; also in the presence of H2O or CH4; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With potassium isopropoxide; isopropyl alcohol; dichloro(benzene)ruthenium(II) dimer; (1S,2R)-N-benzylnorephedrine at 20℃; for 0.33h; Title compound not separated from byproducts; | |
| With dichloro(benzene)ruthenium(II) dimer; 2-benzylamino-1-phenyl-propan-1-ol; potassium isopropoxide In isopropyl alcohol at 20℃; for 0.33h; Title compound not separated from byproducts; |
Conditions
| Conditions | Yield |
|---|---|
| With vinyl acetate; Candida antarctica B lipase on carrier C3 In hexane at 37℃; for 20h; Title compound not separated from byproducts; | |
| With pentyl cage-coated capillary column Resolution of racemate; | |
| With homochiral metal-organic cage [Zn3(deprotonated [3+3] macrocyclic Schiff base of trans-1,2-diaminocyclohexane and 4-tert-butyl-2,6-diformylphenol)2] coated capillary column In dichloromethane at 115℃; Resolution of racemate; enantioselective reaction; |
(R)-(-)-1-METHOXY-2-PROPANOL Chemical Properties
Molecular Formula: C4H10O2
Molar mass: 90.12 g/mol
Density: 0.921 g/mL at 20 °C(lit.)
Flash Point: 33 °C
Melting point: -97 °C
storage temp: Flammables area
Boiling Point: 119-121 °C(lit.)
Index of Refraction: n20/D 1.403
Appearance: Colorless to light yellow liqui
Structure of (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) :
Synonyms of (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) : (R)-(-)-Propylene glycol 1-methyl ether
Product Categories : Chiral Compound
Molar mass: 90.12 g/mol
Density: 0.921 g/mL at 20 °C(lit.)
Flash Point: 33 °C
Melting point: -97 °C
storage temp: Flammables area
Boiling Point: 119-121 °C(lit.)
Index of Refraction: n20/D 1.403
Appearance: Colorless to light yellow liqui
Structure of (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) :
Synonyms of (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) : (R)-(-)-Propylene glycol 1-methyl ether
Product Categories : Chiral Compound
(R)-(-)-1-METHOXY-2-PROPANOL Toxicity Data With Reference
Carcinogenicity of (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65.And its toxicological properties have not been fully investigated.
(R)-(-)-1-METHOXY-2-PROPANOL Safety Profile
Hazard Note: Irritant Toxic
Hazard Codes: F
,Xn
Risk Statements:
10: Flammable
15: Contact with water liberates extremely flammable gases
Safety Statements:
7: Keep container tightly closed
8: Keep container dry
24: Avoid contact with skin
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
Hazard Codes: F
,XnRisk Statements:
10: Flammable
15: Contact with water liberates extremely flammable gases
Safety Statements:
7: Keep container tightly closed
8: Keep container dry
24: Avoid contact with skin
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
(R)-(-)-1-METHOXY-2-PROPANOL Specification
(R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) is hazardous,so the first aid measures and others should be known .Such as:
Skin: Get medical aid. Should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing and shoes.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.
Inhalation: Remove from exposure and move to fresh air immediately. when breathing is difficult, give oxygen.And as soon as to get medical aid.
Ingestion: Wash mouth out with water,and get medical aid immediately.
Notes to Physician: Treat supportively and symptomatically.
Polymerization of the (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, and you must not take it with ignition sources and incompatible materials.And also prevent it to broken down into hazardous decomposition products: carbon dioxide,carbon monoxide.
Skin: Get medical aid. Should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing and shoes.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.
Inhalation: Remove from exposure and move to fresh air immediately. when breathing is difficult, give oxygen.And as soon as to get medical aid.
Ingestion: Wash mouth out with water,and get medical aid immediately.
Notes to Physician: Treat supportively and symptomatically.
Polymerization of the (R)-(-)-1-METHOXY-2-PROPANOL(4984-22-9) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, and you must not take it with ignition sources and incompatible materials.And also prevent it to broken down into hazardous decomposition products: carbon dioxide,carbon monoxide.
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(R)-(-)-1-METHOXY-2-PROPANOL
