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Name |
(Z)-11-Hexadecenol |
EINECS | N/A |
CAS No. | 56683-54-6 | Density | 0.847±0.06 g/cm3 (20 ºC 760 Torr) |
PSA | 20.23000 | LogP | 5.23600 |
Solubility | N/A | Melting Point |
N/A |
Formula | C16H32 O | Boiling Point | 309°C at 760 mmHg |
Molecular Weight | 240.429 | Flash Point | 134.9°C |
Transport Information | N/A | Appearance | N/A |
Safety | Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors. | Risk Codes | N/A |
Molecular Structure | Hazard Symbols | Low toxicity by ingestion. | |
Synonyms |
11-Hexadecen-1-ol,(Z)-; (Z)-11-Hexadecen-1-ol; (Z)-11-Hexadecenol; cis-11-Hexadecen-1-ol |
Article Data | 40 |
(Z)-11-hexadecen-1-yl acetate
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 1h; Heating; | 97% |
Hydrolysis; | |
With Tris-HCl buffer; antennal esterase from Sesamia nonagrioides In ethanol at 32℃; for 1h; pH=8.0; Enzyme kinetics; |
(11Z)-hexadec-11-enoic acid
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In diethyl ether for 5h; | 96% |
11-hexadecyn-1-ol
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With bis(cyclopentadienyl)titanium dichloride; isobutylmagnesium bromide | 92% |
With sodium tetrahydroborate; Ni(CH3CO2)4H2O; hydrogen; diethylamine In ethanol | 91% |
With hydrogen; P2Ni | 87% |
(Z)-2-(hexadec-11-en-1-yloxy)tetrahydro-2H-pyran
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In ethanol at 80℃; | 92% |
With pyridinium p-toluenesulfonate In methanol at 55℃; for 6h; | 52% |
With hydrogenchloride In methanol |
Conditions | Yield |
---|---|
With C32H41N3O4Ru In tetrahydrofuran at 20℃; Inert atmosphere; Glovebox; chemoselective reaction; | 76% |
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With polytetrafluoroethylene; pentanal; sodium ethanolate In tetrahydrofuran at 90 - 95℃; for 24h; | 75% |
Conditions | Yield |
---|---|
With CYP52A13 hydroxylase enzyme; oxygen In water at 30℃; Reagent/catalyst; | A 74.4% B 27.6% |
With CYP52A3 hydroxylase enzyme; oxygen In water at 30℃; Reagent/catalyst; | A 33.2% B 66.8% |
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; ethyl acetate; calcium chloride In tetrahydrofuran 1.) reflux, 12 h then rt., 48 h; 2.) reflux, 7 h; 3.) 1.5 h; | 68% |
With sodium hydroxide; calcium borohydride; dihydrogen peroxide; ethyl acetate In tetrahydrofuran for 7h; Product distribution; Mechanism; Heating; var. alkene, metal borohydride; | 68% |
pentanal
(11‑hydroxyundecyl)triphenylphosphonium bromide
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
Stage #1: (11‑hydroxyundecyl)triphenylphosphonium bromide With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Schlenk technique; Stage #2: pentanal In tetrahydrofuran at 20℃; for 24h; | 54% |
With sodium amide 1.) THF, 25 deg C, 30 min, 2.) -80 deg C to 25 deg C, 15 min; Yield given. Multistep reaction; |
(11Z)-hexadeca-1,11-diene
(Z)-11-hexadecen-1-ol
Conditions | Yield |
---|---|
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran | |
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide 1. THF, r.t., 5 h, 2. r.t., 17 h; Yield given. Multistep reaction; |
Chemistry informtion about (Z)-11-Hexadecenol (CAS NO.56683-54-6) is:
IUPAC Name: (Z)-Hexadec-11-En-1-Ol
Synonyms: (Z)-Hexadec-11-En-1-Ol ; Cis-11-Hexadecanol ; (Z)-11-Hexadecenol ; (11z)-11-Hexadecen-1-Ol ; (Z)-11-Hexadecen-1-Ol
MF: C16H32O
MW: 240.42468
EINECS: 260-337-6
Density: 0.847 g/cm3
Flash Point: 134.9 °C
Boiling Point: 309 °C at 760 mmHg
Vapour Pressure: 5.97E-05 mmHg at 25°C
Enthalpy of Vaporization: 63.74 kJ/mol
Following is the molecular structure of (Z)-11-Hexadecenol (CAS NO.56683-54-6) is:
1. | orl-rat LD50:>5600 mg/kg | HBPTO* Handbook of pesticide toxicology. 1 (2001),142. |
Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.