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(Z)-11-Hexadecenol

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Name

(Z)-11-Hexadecenol

EINECS N/A
CAS No. 56683-54-6 Density 0.847±0.06 g/cm3 (20 ºC 760 Torr)
PSA 20.23000 LogP 5.23600
Solubility N/A Melting Point N/A
Formula C16H32 O Boiling Point 309°C at 760 mmHg
Molecular Weight 240.429 Flash Point 134.9°C
Transport Information N/A Appearance N/A
Safety Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors. Risk Codes N/A
Molecular Structure Molecular Structure of 56683-54-6 ((Z)-hexadec-11-en-1-ol) Hazard Symbols Low toxicity by ingestion.
Synonyms

11-Hexadecen-1-ol,(Z)-; (Z)-11-Hexadecen-1-ol; (Z)-11-Hexadecenol; cis-11-Hexadecen-1-ol

Article Data 40

(Z)-11-Hexadecenol Synthetic route

34010-21-4

(Z)-11-hexadecen-1-yl acetate

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 1h; Heating;97%
Hydrolysis;
With Tris-HCl buffer; antennal esterase from Sesamia nonagrioides In ethanol at 32℃; for 1h; pH=8.0; Enzyme kinetics;
2416-20-8

(11Z)-hexadec-11-enoic acid

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether for 5h;96%
65686-49-9

11-hexadecyn-1-ol

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With bis(cyclopentadienyl)titanium dichloride; isobutylmagnesium bromide92%
With sodium tetrahydroborate; Ni(CH3CO2)4H2O; hydrogen; diethylamine In ethanol91%
With hydrogen; P2Ni87%
99159-89-4

(Z)-2-(hexadec-11-en-1-yloxy)tetrahydro-2H-pyran

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In ethanol at 80℃;92%
With pyridinium p-toluenesulfonate In methanol at 55℃; for 6h;52%
With hydrogenchloride In methanol
592-41-6

1-hexene

68760-58-7

11-eicosenol

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With C32H41N3O4Ru In tetrahydrofuran at 20℃; Inert atmosphere; Glovebox; chemoselective reaction;76%

tetrakis(11-hydroxyundecyl)phosphanium bromide

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With polytetrafluoroethylene; pentanal; sodium ethanolate In tetrahydrofuran at 90 - 95℃; for 24h;75%
69820-25-3

(Z)-hexadec-5-ene

A

56683-54-6

(Z)-11-hexadecen-1-ol

B

106463-48-3

Δ5-hexadecenol

Conditions
ConditionsYield
With CYP52A13 hydroxylase enzyme; oxygen In water at 30℃; Reagent/catalyst;A 74.4%
B 27.6%
With CYP52A3 hydroxylase enzyme; oxygen In water at 30℃; Reagent/catalyst;A 33.2%
B 66.8%

1,11-hexadecadiene

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; ethyl acetate; calcium chloride In tetrahydrofuran 1.) reflux, 12 h then rt., 48 h; 2.) reflux, 7 h; 3.) 1.5 h;68%
With sodium hydroxide; calcium borohydride; dihydrogen peroxide; ethyl acetate In tetrahydrofuran for 7h; Product distribution; Mechanism; Heating; var. alkene, metal borohydride;68%
110-62-3

pentanal

19101-00-9

(11‑hydroxyundecyl)triphenylphosphonium bromide

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
Stage #1: (11‑hydroxyundecyl)triphenylphosphonium bromide With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: pentanal In tetrahydrofuran at 20℃; for 24h;
54%
With sodium amide 1.) THF, 25 deg C, 30 min, 2.) -80 deg C to 25 deg C, 15 min; Yield given. Multistep reaction;
65734-21-6, 82294-54-0

(11Z)-hexadeca-1,11-diene

56683-54-6

(Z)-11-hexadecen-1-ol

Conditions
ConditionsYield
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide 1. THF, r.t., 5 h, 2. r.t., 17 h; Yield given. Multistep reaction;

(Z)-11-Hexadecenol Chemical Properties

Chemistry informtion about (Z)-11-Hexadecenol (CAS NO.56683-54-6) is:
IUPAC Name: (Z)-Hexadec-11-En-1-Ol
Synonyms: (Z)-Hexadec-11-En-1-Ol ; Cis-11-Hexadecanol ; (Z)-11-Hexadecenol ; (11z)-11-Hexadecen-1-Ol ; (Z)-11-Hexadecen-1-Ol
MF: C16H32O
MW: 240.42468
EINECS: 260-337-6 
Density: 0.847 g/cm3
Flash Point: 134.9 °C
Boiling Point: 309 °C at 760 mmHg
Vapour Pressure: 5.97E-05 mmHg at 25°C 
Enthalpy of Vaporization: 63.74 kJ/mol
Following is the molecular structure of (Z)-11-Hexadecenol (CAS NO.56683-54-6) is:

(Z)-11-Hexadecenol Toxicity Data With Reference

1.    

orl-rat LD50:>5600 mg/kg

    HBPTO*    Handbook of pesticide toxicology. 1 (2001),142.

(Z)-11-Hexadecenol Safety Profile

Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.

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