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1,2,3-TRICHLOROPROPANE

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1,2,3-TRICHLOROPROPANE

EINECS 202-486-1
CAS No. 96-18-4 Density 1.309 g/cm3
Solubility water: 2 g/L (25 °C) Melting Point -14 °C
Formula C3H5Cl3 Boiling Point 156.8 °C at 760 mmHg
Molecular Weight 147.43 Flash Point 82.2 °C
Transport Information UN 2810 6.1/PG 3 Appearance Clear colorless to pale yellow liquid
Safety 53-45-36/37-37-36 Risk Codes 45-60-20/21/22-39/23/24/25-23/24/25-11-38
Molecular Structure Molecular Structure of 96-18-4 (1,2,3-TRICHLOROPROPANE) Hazard Symbols ToxicT,FlammableF
Synonyms

Allyl trichloride;Glycerol trichlorohydrin;NSC35403;Trichlorohydrin;

 

1,2,3-TRICHLOROPROPANE Chemical Properties

IUPAC Name: 1,2,3-Trichloropropane
The MF of 1,2,3-Trichloropropane (96-18-4) is C3H5Cl3.

                           
The MW of 1,2,3-Trichloropropane (96-18-4) is 147.43.
Synonyms of 1,2,3-Trichloropropane (96-18-4): 1,2,3-Trichloro-propan ; 1,2,3-Trichlorpropan ; Allyl trichloride ; Allyltrichloride ; Glycerintrichlorhydrin ; Glyceryl trichlorohydrin ; Glyceryltrichlorohydrin 
Product Categories: Organics;Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Standard Solutions (VOC);Method 552Volatiles/ Semivolatiles;500 Series Drinking Water Methods;ChloroEPA;EPA
Form: Clear colorless to pale yellow liquid
Water Solubility: 2 g/L (25 ºC)
Index of Refraction: 1.453 
EINECS: 202-486-1
Density: 1.309 g/ml 
Flash Point: 82.2 °C
Boiling Point: 156.8 °C
Melting Point: -14 °C
Storage temp: -20 °C 
BRN: 1732068

1,2,3-TRICHLOROPROPANE Uses

   1,2,3-Trichloropropane (96-18-4) is used to produce 1,2,3-allyl chloride and also a good solvent. Also for pesticides chlormequat and oats enemy raw materials.

1,2,3-TRICHLOROPROPANE Production

 1,2,3-Trichloropropane is sensitive to prolonged exposure to light. Sensitive to heat. May react with active metals, strong caustics and oxidizing agents. Attacks some plastics, rubber and some coatings.High-temperature chlorination of propylene was allyl chloride by washing, separation, and then by low-temperature chlorination, fractionation, that was finished.

1,2,3-TRICHLOROPROPANE Toxicity Data With Reference

1.    

skn-rbt 700 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973.
2.    

eye-rbt 140 mg SEV

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973.
3.    

mmo-sat 100 nmol/plate

    ENMUDM    Environmental Mutagenesis. 2 (1980),59.
4.    

mma-sat 500 ng/plate

    ENMUDM    Environmental Mutagenesis. 7 (Suppl 3)(1985),15.
5.    

orl-rat LD50:320 mg/kg

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973.
6.    

ihl-rat LCLo:1000 ppm/4H

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
7.    

ihl-mus LC50:3400 mg/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,114.
8.    

orl-dog LDLo:200 mg/kg

    AJHYA2    American Journal of Hygiene. 16 (1932),325.
9.    

skn-rbt LD50:1770 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.

1,2,3-TRICHLOROPROPANE Consensus Reports

NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory.

1,2,3-TRICHLOROPROPANE Safety Profile

Confirmed carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Experimental reproductive effects. A skin and severe eye irritant. Mutation data reported. Moderately flammable by heat, flames (sparks), or powerful oxidizers. See also ALLYL COMPOUNDS and CHLORINATED HYDROCARBONS, ALIPHATIC. When heated to decomposition it yields highly toxic Cl. To fight fire, use water (as a blanket), spray, mist, dry chemical.Safety information of 1,2,3-Trichloropropane (96-18-4):
Hazard Codes  T,F
Risk Statements 
45  May cause cancer
60  May impair fertility
20/21/22  Harmful by inhalation, in contact with skin and if swallowed
39/23/24/25  Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
11  Highly Flammable
38  Irritating to the skin
Safety Statements 
53  Avoid exposure - obtain special instruction before use
45  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37  Wear suitable protective clothing and gloves
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  TZ9275000
HazardClass  6.1
PackingGroup  III
HS Code  29031980

1,2,3-TRICHLOROPROPANE Standards and Recommendations

OSHA PEL: TWA 10 ppm
ACGIH TLV: TWA 10 ppm (skin); Animal Carcinogen
DFG MAK: Confirmed Animal Carcinogen, Suspected Human Carcinogen

1,2,3-TRICHLOROPROPANE Analytical Methods

For occupational chemical analysis use NIOSH: Hydrocarbons, Halogenated, 1003.

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