Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

1,3-Diphenylacetone
Related Products

Hot Products

Basic Information Post buying leads Suppliers Cas Database
Name

1,3-Diphenylacetone

 EINECS 203-000-0
CAS No. 102-04-5 Density 1.069 g/cm3
PSA 17.07000 LogP 3.04090
Solubility Slightly soluble in water. Melting Point 32-34 °C(lit.)
Formula C15H14O Boiling Point 331 °C at 760 mmHg
Molecular Weight 210.276 Flash Point 149.4 °C
Transport Information N/A Appearance light yellow solid
Safety 24/25-22 Risk Codes N/A
Molecular Structure Molecular Structure of 102-04-5 (1,3-Diphenylacetone) Hazard Symbols N/A
Synonyms

1,3-Diphenyl-2-propanone;2-Propanone,1,3-diphenyl-;1,3-Diphenylpropanone;Benzyl ketone;Dibenzyl ketone;NSC220312;NSC 407392;NSC 4577;a,a'-Diphenylacetone;

Article Data 214

1,3-Diphenylacetone Synthetic route

76312-47-5

2,2-bis(benzyl)-1,3-dithiolane

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With trichloroisocyanuric acid; silver nitrate In water; acetonitrile Ambient temperature;99%
With (CH3)3CI; dimethyl sulfoxide for 12h;95%
With trimethylsilyl iodide; dimethyl sulfoxide In tetrachloromethane at 75 - 80℃; for 6h;85%
With hydrogenchloride; dihydrogen peroxide In methanol Ambient temperature;81%

C27H24S2

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 20 - 25℃; for 2h; Irradiation;98%
4362-53-2

1,3-diphenyl-2-propanone ethylene acetal

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With chloral hydrate In hexane at 25℃; for 5h; Inert atmosphere;98%
1788-30-3

phenylhydrazone of dibenzyl ketone

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With copper(II) sulfate In tetrahydrofuran; methanol; water for 4h; Heating;95%
19689-93-1

1,3-Diphenylpropanone oxime O-acetate

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
Stage #1: 1,3-Diphenylpropanone oxime O-acetate With dicobalt octacarbonyl; triethylamine In diethyl ether at 20℃; for 0.25h; deoximation;
Stage #2: With water In methanol at 20℃; for 0.5h; Hydrolysis;		93%
With diiron nonacarbonyl In methanol at 60℃; for 1h; Product distribution; Fe(CO)5, UV irradiation;82%
101587-37-5

1,3-diphenylacetone N,N-dimethylhydrazone

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetic acid; acetonitrile at 0 - 20℃; Product distribution; oxidative cleavage;93%
With porcin pancreatic lipase In water; acetone at 20℃; for 96h; Hydrolysis;94 % Chromat.
85855-49-8

1,3-diphenyl-1-phenylsulfanylpropan-2-one

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With zinc In acetic acid92%
462-06-6

fluorobenzene

67-64-1

acetone

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With n-butyllithium at -78℃; for 8h;92%
1788-31-4

1,3-diphenylpropan-2-one oxime

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With copper(II) sulfate In tetrahydrofuran; methanol; water for 19h; Heating;90%
With iron pentacarbonyl In methanol for 48h; Product distribution; Irradiation; Fe2(CO)9, 60 deg C;81%
With water; oxygen In acetonitrile at 60℃; under 760.051 Torr; for 6h; Autoclave; Green chemistry;32%
With bismuth(lll) trifluoromethanesulfonate; bismuth(III) bromide In water; acetone; acetonitrile for 4h; Heating;
Multi-step reaction with 2 steps
1: acetic acid; chlorine
2: NaN3; aqueous acetic acid; CO2
View Scheme
100-39-0

benzyl bromide

103-80-0

phenylacetyl chloride

102-04-5

1,3-Diphenylpropanone

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel(0); 4,4'-di-tert-butyl-2,2'-bipyridine; magnesium chloride; zinc In acetonitrile at 25℃; for 12h; Inert atmosphere;90%
With bis(1,5-cyclooctadiene)nickel(0); 4,4'-di-tert-butyl-2,2'-bipyridine; magnesium chloride; zinc In acetonitrile at 25℃; for 12h; Schlenk technique; Inert atmosphere;90%
With tetrabutylammonium tetrafluoroborate; (2,2'-bipyridine)nickel(II) dibromide In acetonitrile Ambient temperature; zinc rod as the anode, vitreous carbon gauze as the cathode, 0.1 A;80%
With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; tris(2,2'-bipyridine)nickel(II) tetrafluoroborate In acetonitrile at 25℃; Product distribution; Kinetics; Electrochemical reaction;
With bis(1,5-cyclooctadiene)nickel(0); magnesium chloride; zinc In acetonitrile at 20℃; for 12h; Inert atmosphere;41 mmol

1,3-Diphenylacetone Chemical Properties

Molecule structure of 1,3-Diphenylacetone (CAS NO.102-04-5):

IUPAC Name: 1,3-Diphenylpropan-2-one 
Molecular Weight: 210.27106 g/mol
Molecular Formula: C15H14O 
Density: 1.069 g/cm3 
Melting Point: 32-34 °C(lit.)
Boiling Point: 331 °C at 760 mmHg
Flash Point: 149.4 °C
Index of Refraction: 1.574
Molar Refractivity: 64.95 cm3
Molar Volume: 196.5 cm3
Surface Tension: 42.1 dyne/cm 
Enthalpy of Vaporization: 57.36 kJ/mol 
Vapour Pressure: 0.00016 mmHg at 25 °C 
Storage Temp.: 2-8 °C
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
XLogP3-AA: 3.1
H-Bond Acceptor: 1
Rotatable Bond Count: 4
Tautomer Count: 2
Exact Mass: 210.104465
MonoIsotopic Mass: 210.104465
Topological Polar Surface Area: 17.1
Heavy Atom Count: 16
Canonical SMILES: C1=CC=C(C=C1)CC(=O)CC2=CC=CC=C2
InChI: InChI=1S/C15H14O/c16-15(11-13-7-3-1-4-8-13)12-14-9-5-2-6-10-14/h1-10H,11-12H2
InChIKey: YFKBXYGUSOXJGS-UHFFFAOYSA-N
EINECS: 203-000-0
Product Categories: Aromatic Ketones (substituted)

1,3-Diphenylacetone Uses

 1,3-Diphenylacetone (CAS NO.102-04-5) is frequently used in an aldol condensation reaction with benzil (a dicarbonyl) and base to create tetraphenylcyclopentadienone.

1,3-Diphenylacetone Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral > 2gm/kg (2000mg/kg) BEHAVIORAL: ATAXIA National Technical Information Service. Vol. OTS0559576,

1,3-Diphenylacetone Safety Profile

Safety Statements: 24/25-22 
S24/25:Avoid contact with skin and eyes. 
S22:Do not breathe dust.
WGK Germany: 3
RTECS: EC2030000

1,3-Diphenylacetone Specification

 1,3-Diphenylacetone (CAS NO.102-04-5) is also named as 1,3-Diphenyl-2-propanone ; 1,3-Diphenylpropanone ; 2-Propanone, 1,3-diphenyl- ; AI3-05001 ; Benzyl ketone ; Dibenzyl ketone ; FEMA No. 2397 ; NSC 220312 ; alpha,alpha'-Diphenylacetone . 1,3-Diphenylacetone (CAS NO.102-04-5) is light yellow solid.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 102-04-5