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Cas Database

Name	1-PROPOXY-2-PROPANOL	EINECS	250-069-8
CAS No.	1569-01-3	Density	0.885 g/mL at 25 °C(lit.)
PSA	29.46000	LogP	0.79380
Solubility	miscible		Melting Point	-80 C
Formula	C6H14 O2	Boiling Point	140 - 160 C
Molecular Weight	118.176	Flash Point	48 C
Transport Information	HAZARD	Appearance	clear liquid
Safety		Risk Codes	R10; R36/37/38
Molecular Structure		Hazard Symbols	UN NO.
Synonyms	1,2-Propyleneglycol 1-propyl ether; 1-Propoxy-2-propanol; Arcosolv PNP	Article Data	22

1-PROPOXY-2-PROPANOL Synthetic route

: 71-23-8
propan-1-ol

: 75-56-9, 16033-71-9
methyloxirane

: 1569-01-3
1-(1-propyloxy)propan-2-ol

Conditions

Conditions	Yield
With Al2O3/MgO composite at 120℃; Inert atmosphere;	34.4%
With KAcMIMOH at 60℃; for 4h;
With hematite at 160℃; for 8h; Autoclave;

: 71-23-8
propan-1-ol

: 75-56-9, 16033-71-9
methyloxirane

A: 10215-30-2
2-propoxy-1-propanol

B: 1569-01-3
1-(1-propyloxy)propan-2-ol

Conditions

Conditions	Yield
at 100 - 200℃;
at 180 - 205℃;
With sulfuric acid Yield given. Yields of byproduct given;

: 6819-41-6
sodium n-propoxide

: 75-56-9, 16033-71-9
methyloxirane

: 1569-01-3
1-(1-propyloxy)propan-2-ol

: 106-92-3
Allyl glycidyl ether

A: 3126-95-2
3-Propoxy-1,2-epoxypropan

B: 1569-01-3
1-(1-propyloxy)propan-2-ol

Conditions

Conditions	Yield
With hydrogen; 5percent Pd/C(en) In tetrahydrofuran at 20℃; for 2.5h; Catalytic hydrogenation; Title compound not separated from byproducts.;

: 57-55-6
propylene glycol

A: 71-23-8
propan-1-ol

B: 111-43-3
Dipropyl ether

C: 10215-30-2
2-propoxy-1-propanol

D: 1569-01-3
1-(1-propyloxy)propan-2-ol

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid; hydrogen; [{CpRu(CO)2}2(μ-H)](+)*OTf(-); cyclopenta-1,3-diene In sulfolane at 110℃; under 39003.1 Torr; for 30h; Product distribution;	A 54 % Chromat. B 15 % Chromat. C n/a D n/a

: 57-55-6
propylene glycol

A: 71-23-8
propan-1-ol

B: 4359-46-0
2-ethyl-4-methyl-1,3-dioxolane

C: 111-43-3
Dipropyl ether

D: 10215-30-2
2-propoxy-1-propanol

E: 1569-01-3
1-(1-propyloxy)propan-2-ol

F: 123-38-6
propionaldehyde

Conditions

Conditions	Yield
With bis(dicarbonyl)(μ-hydrido)(pentamethylcyclopentadiene)ruthenium trifluoromethanesulfonate; trifluorormethanesulfonic acid; hydrogen In sulfolane at 110℃; under 38787.1 Torr; for 30h; Mechanism; Kinetics; Solvent; Pressure; Concentration; Temperature; Time; regioselective reaction;	A 54 %Chromat. B n/a C n/a D n/a E n/a F n/a

...Expand

: 57-55-6
propylene glycol

A: 71-23-8
propan-1-ol

B: 106-36-5
propyl propionate

C: 74-98-6
propane

D: 10215-30-2
2-propoxy-1-propanol

E: 1569-01-3
1-(1-propyloxy)propan-2-ol

F: 802294-64-0
propionic acid

G: 108-67-8
1,3,5-trimethyl-benzene

Conditions

Conditions	Yield
With [C6H3-2,6-(OP(tBu)2)2]IrH2; trifluorormethanesulfonic acid; hydrogen In 1,4-dioxane at 125℃; under 5171.62 Torr; Autoclave;

...Expand

: 1-propoxy-2-propanyl formate

A: 64-18-6
formic acid

B: 1569-01-3
1-(1-propyloxy)propan-2-ol

Conditions

Conditions	Yield
With water at 80℃; for 24h; Equilibrium constant; Sealed tube;

: 1569-01-3
1-(1-propyloxy)propan-2-ol

: 1056233-21-6
N’-(5-bromo-6-hydroxy-2-methyl-3-pyridyl)-N-ethyl-N-methyl-formamidine

: N’-[5-bromo-2-methyl-6-[1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20 - 40℃; for 1.66667h; Inert atmosphere;	95%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;	95%

: 67-56-1
methanol

: 1569-01-3
1-(1-propyloxy)propan-2-ol

: 1-propoxy-2-propanyl formate

Conditions

Conditions	Yield
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II); methacrylic acid methyl ester In toluene at 140℃; under 13689.1 Torr; for 4h; Autoclave; Inert atmosphere;	71%

1-PROPOXY-2-PROPANOL Chemical Properties

Synonyms: PNP;2-Propanol, 1-propoxy-;PROPYLENE GLYCOL PROPYL ETHER;PROPYLENE GLYCOL MONOPROPYL ETHER;PROPYLENE GLYCOL NORMAL PROPYL ETHER;ethermonopropyliquenormaldupropyleneglycol ;1-propoxy-2-propano;1-propoxy-propan-2-ol;
The Molecular formula of 1-PROPOXY-2-PROPANOL(1569-01-3): C₆H₁₄O₂
The Molecular Weight of 1-PROPOXY-2-PROPANOL(1569-01-3): 118.17
Molecular Structure :

EINECS: 216-372-4
Boiling point: 140-160 °C(lit.)
Flash point: 119 °F
density: 0.885 g/mL at 25 °C(lit.)
refractive index: n20/D 1.411(lit.)

1-PROPOXY-2-PROPANOL Toxicity Data With Reference

1.	skn-rbt 500 mg	VHTODE Veterinary and Human Toxicology. 30 (1988),126.
2.	eye-rbt 100 mg MOD	VHTODE Veterinary and Human Toxicology. 30 (1988),126.
3.	orl-rat LD50:2504 mg/kg	VHTODE Veterinary and Human Toxicology. 30 (1988),126.
4.	skn-rbt LD50:3550 mg/kg	38MKAJ Pattys Industrial Hygiene and Toxicology. 2C (1982),3983.

1-PROPOXY-2-PROPANOL Consensus Reports

Reported in EPA TSCA Inventory.

1-PROPOXY-2-PROPANOL Safety Profile

Moderately toxic by ingestion and skin contact. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
The Hazard Codes of 1-PROPOXY-2-PROPANOL(1569-01-3):

Xi
The Risk Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
10: Flammable
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 1-PROPOXY-2-PROPANOL(1569-01-3):
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
RIDADR: UN 3271 3/PG 3

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