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2-Deoxy-D-ribose

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Name

2-Deoxy-D-ribose

EINECS 208-573-0
CAS No. 533-67-5 Density 1.516 g/cm3
PSA 69.92000 LogP -1.55310
Solubility soluble in water Melting Point 89-90 °C(lit.)
Formula C5H10O4 Boiling Point 379.684 °C at 760 mmHg
Molecular Weight 134.132 Flash Point 197.601 °C
Transport Information N/A Appearance white to off-white crystalline powder
Safety 24/25-37/39-36-26 Risk Codes 20/21/22-36/37/38
Molecular Structure Molecular Structure of 533-67-5 (2-Deoxy-D-ribose) Hazard Symbols HarmfulXn, IrritantXi
Synonyms

Thyminose;2.2-deoxy-D-ribose;(3R,4S)-3,4,5-trihydroxypentanal;2-Deoxyribose;2-Deoxy-alpha-D-ribopyranose;3,4,5-trihydroxypentanal;(3R,4R)-3,4,5-trihydroxypentanal;D-erythro-Pentose,2-deoxy-;2-Deoxy-beta-D-erythro-pentose;2-deoxy-d-ribose/thyminose;Deoxy-Ribose;2-Deoxy-D-arabinose;D-erythro-Pentose;

Article Data 52

2-Deoxy-D-ribose Synthetic route

93857-40-0

sodium 3-deoxy-D-mannonate

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
Stage #1: sodium 3-deoxy-D-mannonate With hydrogenchloride In water pH=5;
Stage #2: With sodium hypochlorite; acetic acid In water at 40 - 45℃; for 2h; pH=5 - 6;
95%
Stage #1: sodium 3-deoxy-D-mannonate With hydrogenchloride In water pH=5;
Stage #2: With hydrogenchloride; sodium hypochlorite; acetaldehyde In water at 40 - 45℃; for 2h; pH=5 - 6;
94%
Stage #1: sodium 3-deoxy-D-mannonate With hydrogenchloride In water pH=5;
Stage #2: With hydrogenchloride; sodium hypochlorite; formaldehyd In water at 40 - 45℃; for 2h; pH=5 - 6;
94%
1518-59-8

D-arabino-3-deoxy-hexonic acid

50480-80-3

3-deoxy-D-arabino-hexono-1,4-lactone

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
Stage #1: D-arabino-3-deoxy-hexonic acid; 3-deoxy-D-arabino-hexono-1,4-lactone With sodium carbonate In water at 20℃; pH=8.8;
Stage #2: With sodium hypochlorite In water for 1 - 4h; pH=4.5 - 5.0;
Stage #3: With sodium sulfite In water
93%
87616-31-7

(S)-2-Amino-6-{3-[(E)-3-((2R,4S,5R)-4-hydroxy-5-hydroxymethyl-tetrahydro-furan-2-ylamino)-2-methyl-acryloyl]-ureido}-hexanoic acid

A

533-67-5

2-Deoxy-D-ribose

B

76945-38-5

(2S)-amino-6-(1-thyminyl)hexanoic acid

Conditions
ConditionsYield
With pH 10.5 In water at 90℃;A n/a
B 90%
17510-99-5

4,5,6-trihydroxy-2-oxohexanoic acid

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
With cerium(IV) sulphate; sulfuric acid; palladium 10% on activated carbon In water at 37℃;51%

potassium 2-dehydro-3-deoxy-D-gluconate

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
Stage #1: potassium 2-dehydro-3-deoxy-D-gluconate With sulfuric acid; hydrogen; palladium 10% on activated carbon In water at 50℃;
Stage #2: With calcium carbonate In water
Stage #3: With calcium hydroxide; carbon dioxide; dihydrogen peroxide; copper diacetate; iron(II) sulfate more than 3 stages;
47%

6,6-bis-ethanesulfonyl-L-erythro-hex-5-ene-1,2,3-triol

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
With ammonium hydroxide
2490-91-7

3-deoxy-D-glucose

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
With sodium periodate; water und anschliessend mit wss.Ammoniak;
50-99-7

D-glucose

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
With calcium hydroxide; water at 120℃; und Behandeln der vom Calciumhydroxid befreiten, mit Eisen(III)-sulfat und Bariumacetat versetzen Loesung des Reaktionsprodukts mit wss.Wasserstoffperoxid;
Conditions
ConditionsYield
With calcium hydroxide; water Erwaermen des Reaktionsprodukts mit Eisen(III)-sulfat,Bariumacetat und wss.Wasserstoffperoxid;
50705-39-0

O3-(toluene-4-sulfonyl)-D-glucose

533-67-5

2-Deoxy-D-ribose

Conditions
ConditionsYield
With calcium hydroxide; water

2-Deoxy-D-ribose Specification

The CAS register number of 2-Deoxy-D-ribose is 533-67-5. It also can be called as 2-Deoxy-D-erythropentose and the IUPAC name about this chemical is 3,4,5-trihydroxypentanal. The molecular formula about this chemical is C5H10O4 and the molecular weight is 134.13. It belongs to the following product categories, such as Pharmaceutical Raw Materials; Fine Chemical & Intermediates; 13C & 2H Sugars; Riboses and 2'-Deoxyriboses; Biochemistry; Deoxysugars; Nucleosides, Nucleotides & Related Reagents; Ribose; Sugars; Dextrins、Sugar & Carbohydrates; aldehydes; Carbohydrates & Derivatives and so on.

Physical properties about 2-Deoxy-D-ribose are: (1)ACD/BCF (pH 5.5): 1; (2)ACD/BCF (pH 7.4): 1; (3)ACD/KOC (pH 5.5): 1.193; (4)ACD/KOC (pH 7.4): 1.193; (5)#H bond acceptors: 4; (6)#H bond donors: 3; (7)#Freely Rotating Bonds: 7; (8)Polar Surface Area: 77.76Å2; (9)Index of Refraction: 1.5; (10)Molar Refractivity: 29.922 cm3; (11)Molar Volume: 101.659 cm3; (12)Polarizability: 11.862x10-24cm3; (13)Surface Tension: 61.7 dyne/cm; (14)Enthalpy of Vaporization: 72.613 kJ/mol; (15)Boiling Point: 379.684 °C at 760 mmHg.

Uses of 2-Deoxy-D-ribose: it can be used to produce lithium 2-deoxy-D-erythro-pentonate at temperature of 40 °C. This reaction will need reagent 3 M KOH, 30 percent H2O2, MgO, 0.1 M LiOH with reaction time of 18 hours. The yield is about 95%.

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed and it is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing, gloves and eye/face protection, you also need avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: C(C=O)[C@@H]([C@@H](CO)O)O
(2)InChI: InChI=1/C5H10O4/c6-2-1-4(8)5(9)3-7/h2,4-5,7-9H,1,3H2/t4-,5+/m0/s1
(3)InChIKey: ASJSAQIRZKANQN-CRCLSJGQBK
(4)Std. InChI: InChI=1S/C5H10O4/c6-2-1-4(8)5(9)3-7/h2,4-5,7-9H,1,3H2/t4-,5+/m0/s1
(5)Std. InChIKey: ASJSAQIRZKANQN-CRCLSJGQSA-N

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