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2-Nitrophenylhydrazine

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2-Nitrophenylhydrazine

EINECS 221-222-6
CAS No. 3034-19-3 Density 1.419 g/cm3
PSA 83.87000 LogP 2.17690
Solubility N/A Melting Point 90-92ºC(194-197.6ºF)
Formula C6H7 N3 O2 Boiling Point 314.3 °C at 760 mmHg
Molecular Weight 153.14 Flash Point 143.9 °C
Transport Information UN 1325 4 Appearance ORANGE TO DARK RED POWDER
Safety Poison by intravenous route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS. Risk Codes R36/37/38 R5
Molecular Structure Molecular Structure of 3034-19-3 (2-Nitrophenylhydrazine) Hazard Symbols IrritantXi
Synonyms

Hydrazine,(o-nitrophenyl)- (6CI,7CI,8CI); (2-Nitrophenyl)hydrazine;(o-Nitrophenyl)hydrazine; 1-Hydrazino-2-nitrobenzene; 2-Hydrazino-1-nitrobenzene;o-(Hydrazino)nitrobenzene

Article Data 15

2-Nitrophenylhydrazine Chemical Properties

Chemistry informtion about 2-Nitrophenylhydrazine (CAS NO.3034-19-3) is:
IUPAC Name: (2-Nitrophenyl)Hydrazine
Synonyms: (O-Nitrophenyl)-Hydrazin ; O-Nitrophenythydrazine ; O-Nitrophenylhydrazine ; 1-(2-Nitrophenyl)Hydrazine ; 2-Nitrophenylhydrazine ; 2-Nitrophenylhydrazine, Moistened With Ca 30% Water, 97% ; 2-Nitrophenylhydrazine (Base And/Or Unspecified Salts) ; 2-Nitrophenylhydrazine 98+%
Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes ; Hydrazines ; Nitrogen Compounds ; Organic Building Blocks 
MF: C6H7N3O2
MW: 153.14
EINECS: 221-222-6 
Density: 1.419 g/cm3 
Melting Point: 91-93 °C(lit.)
Flash Point: 143.9 °C
Boiling Point: 314.3 °C at 760 mmHg
Vapour Pressure: 0.000469 mmHg at 25°C 
Enthalpy of Vaporization: 55.55 kJ/mol
Storage temp.:  2-8°C
Sensitive: Light Sensitive
BRN: 512797 
Following is the molecular structure of 2-Nitrophenylhydrazine (CAS NO.3034-19-3) is:

2-Nitrophenylhydrazine Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 178mg/kg (178mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00632,

2-Nitrophenylhydrazine Safety Profile

Poison by intravenous route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Hazard Codes:
IrritantXi
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
RIDADR: UN 1325 4.1/PG 2
WGK Germany: -
RTECS: MV8210000
F:
F 4.6: Do not heat over 60°C. 
F 8: Photosensitive.
HazardClass: 4.1
PackingGroup: III

2-Nitrophenylhydrazine Specification

2-Nitrophenylhydrazine (CAS NO.3034-19-3) is a orange to orange-brown powder.
First Aid Measures:
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively. 
Handling and Storage
Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Flammables-area. Keep refrigerated. (Store below 4°C/39°F.) Store protected from light.

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