Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

3-Chloro-2-methylpropene

Related Products

Hot Products

Name

3-Chloro-2-methylpropene

EINECS 209-251-2
CAS No. 563-47-3 Density 0.897 g/cm3
PSA 0.00000 LogP 1.80130
Solubility 0.5 g/L (20 °C) in water Melting Point -80 °C
Formula C4H7Cl Boiling Point 72.5 °C at 760 mmHg
Molecular Weight 90.5526 Flash Point 9 °F
Transport Information UN 2554 3/PG 2 Appearance clear liquid
Safety 9-16-29-36/37/39-45-61-26 Risk Codes 11-20/22-34-43-51/53
Molecular Structure Molecular Structure of 563-47-3 (3-Chloro-2-methylpropene) Hazard Symbols FlammableF, CorrosiveC, DangerousN
Synonyms

Propene,3-chloro-2-methyl- (6CI,8CI);1-Chloro-2-methyl-2-propene;2-(Chloromethyl)-1-propene;2-Methallyl chloride;2-Methyl-2-propenyl chloride;2-Methyl-3-chloro-1-propene;2-Methyl-3-chloropropene;2-Methylallyl chloride;3-Chloro-2-methyl-1-propene;1-Propene,3-chloro-2-methyl-;Isobutenyl chloride;Methallyl chloride;Methylallyl chloride;NSC 7303;b-Methallyl chloride;g-Chloroisobutylene;

Article Data 60

3-Chloro-2-methylpropene Synthetic route

513-42-8

3-hydroxy-2-methyl-1-propene

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine In sulfolane from 10 deg C to room temp.;95.7%
With pyridine; bis(trichloromethyl) carbonate In tetrahydrofuran Ambient temperature;65%
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine In sulfolane from 10 deg C to room temp., effect of reagents ratio and solvent volume discussed;
32670-93-2

2-methallyl diphenylphosphate

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With lithium chloride In N,N-dimethyl-formamide for 0.166667h; Ambient temperature;64%

Pd(CH2CHCH2)(C6H3Cl2)(As(C6H5)3)

107-05-1

3-chloroprop-1-ene

A

90220-53-4

CH2CHCH2C6H3Cl2

B

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
In dichloromethane O°C, AsPh3 was added, 24 h.;A 55%
B 20%
In dichloromethane O°C, AsPh3 was added, 1.33 h.;A 22%
B 2%
In dichloromethane O°C, AsPh3 was added, 0.67 h.;A 10%
B 0%
In dichloromethane O°C, AsPh3 was added, 0.33 h.;A 6%
B 0%
78538-54-2

boric acid trimethallyl ester

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With boron trichloride at 120℃;
628-56-8

isopropenylmethyl ether

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With hydrogenchloride; copper(l) chloride at 30 - 50℃; under 89731.9 Torr;
36942-09-3

N,N-dichlorourea

64-19-7

acetic acid

115-11-7

isobutene

A

57576-87-1

acetic acid-(chloro-tert-butyl ester)

B

563-47-3

3-Chloro-2-methylpropene

36942-09-3

N,N-dichlorourea

115-11-7

isobutene

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With acetic acid
With trichloroacetic acid
With chloroacetic acid
473-29-0

N,N-Dichlorobenzenesulfonamide

60-29-7

diethyl ether

115-11-7

isobutene

107-07-3

2-chloro-ethanol

A

55982-53-1

1-chloro-2-(2-chloroethoxy)-2-methylpropane

B

563-47-3

3-Chloro-2-methylpropene

115-11-7

isobutene

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
Chlorierung;
With chlorine at 0 - 70℃;
With chlorine at 0℃;
115-11-7

isobutene

A

513-37-1

2-methylprop-1-enyl chloride

B

594-37-6

1,2-dichloro-2-methylpropane

C

507-20-0

tertiary butyl chloride

D

563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
at 80℃; Chlorierung;
With chlorine In tetrachloromethane at 20℃;A n/a
B 6 % Chromat.
C n/a
D 77 % Chromat.

3-Chloro-2-methylpropene Chemical Properties

The molecular structure of 3-Chloro-2-methylpropene (CAS NO.563-47-3):

IUPAC Name: 3-Chloro-2-methylprop-1-ene 
Molecular Weight: 90.55138 g/mol
Molecular Formula: C4H7Cl 
Density: 0.897 g/cm3 
Melting Point: -80 °C
Boiling Point: 72.5 °C at 760 mmHg 
Flash Point: 9 °F
Index of Refraction: 1.41
Molar Refractivity: 24.99 cm3
Molar Volume: 100.8 cm3 
Surface Tension: 20.6 dyne/cm
Enthalpy of Vaporization: 30.08 kJ/mol
Vapour Pressure: 130 mmHg at 25 °C 
Storage Temp.: refrigerator (+4 °C) + flammables area
Water Solubility: 0.5 g/L (20 °C)
XLogP3-AA: 2.1
Rotatable Bond Count: 1
Exact Mass: 90.023628
MonoIsotopic Mass: 90.023628
Canonical SMILES: CC(=C)CCl
InChI: InChI=1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
InChIKey: OHXAOPZTJOUYKM-UHFFFAOYSA-N
EINECS: 209-251-2
Product Categories: Industrial/Fine Chemicals

3-Chloro-2-methylpropene Uses

 3-Chloro-2-methylpropene (CAS NO.563-47-3) is used to make plastics and pharmaceuticals. It is important organic intermediates. It also can be widely used in medicine, pesticides, perfume, synthetic materials.

3-Chloro-2-methylpropene Toxicity Data With Reference

1.    

mmo-sat 6 µmol/plate

    BCPCA6    Biochemical Pharmacology. 29 (1980),2611.
2.    

dns-hmn:hla 1 mmol/L

    CALEDQ    Cancer Letters (Shannon, Ireland). 20 (1983),263.
3.    

orl-rat TDLo:77,250 mg/kg/2Y-I:CAR

    NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.
4.    

orl-mus TDLo:51,500 mg/kg/2Y-I:CAR

    NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.
5.    

orl-rat TD:77,250 mg/kg/2Y-I:NEO,REP

    NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.

3-Chloro-2-methylpropene Consensus Reports

NTP 10th Report on Carcinogens. NTP Carcinogenesis Studies (gavage); Clear Evidence: mouse, rat NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986. . Reported in EPA TSCA Inventory.

3-Chloro-2-methylpropene Safety Profile

Hazard Codes: FlammableF, CorrosiveC, DangerousN
Risk Statements: 11-20/22-34-43-51/53 
R11:Highly flammable. 
R20/22:Harmful by inhalation and if swallowed. 
R34:Causes burns. 
R43:May cause sensitization by skin contact. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 9-16-29-36/37/39-45-61-26 
S9:Keep container in a well-ventilated place. 
S16:Keep away from sources of ignition. 
S29:Do not empty into drains. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 2554 3/PG 2
WGK Germany: 2
RTECS: UC8050000
HazardClass: 3
PackingGroup: II
HS Code: 29032900
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

3-Chloro-2-methylpropene Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
DOT Classification:  3; Label: Flammable Liquid

3-Chloro-2-methylpropene Specification

 3-Chloro-2-methylpropene (CAS NO.563-47-3) is also named as 1-Chloro-2-methyl-2-propene ; 2-Methallyl chloride ; 2-Methyl-2-propenyl chloride ; 2-Methyl-allylchlorid ; 2-Methyl-allylchlorid [German] ; 3-Chlor-2-methyl-prop-1-en ; 3-Chlor-2-methyl-prop-1-en [German] ; 3-Chloro-2-methyl-1-propene ; 3-Chloroisobutylene ; 3-Cloro-2-metil-prop-1-ene ; 3-Cloro-2-metil-prop-1-ene [Italian] ; 4-01-00-00803 (Beilstein Handbook Reference) ; AI3-14901 ; BRN 0878160 ; CCRIS 869 ; Chlorue de methallyle ; Chlorue de methallyle [French] ; Chlorure de methallyle ; Chlorure de methallyle [French] ; Cloruro di metallile ; Cloruro di metallile [Italian] ; HSDB 1149 ; Isobutenyl chloride ; MAC ; Methallyl chloride ; NCI-C54820 ; NSC 7303 ; Propene, 3-chloro-2-methyl- ; beta-Methylallyl chloride ; gamma-Chloroisobutylene . 3-Chloro-2-methylpropene (CAS NO.563-47-3) is clear liquid with a sharp penetrating odor. It is insoluble in water. It may be toxic by ingestion. Irritating to skin and eyes. It is highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. It is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. It is incompatible with strong bases.Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach. 

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 563-47-3