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3-Diethylaminopropylamine

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Name

3-Diethylaminopropylamine

EINECS 203-236-4
CAS No. 104-78-9 Density 0.84 g/cm3
PSA 29.26000 LogP 1.37730
Solubility miscible with water Melting Point -60 °C
Formula C7H18N2 Boiling Point 170.7 °C at 760 mmHg
Molecular Weight 130.233 Flash Point 58.9 °C
Transport Information UN 2684 3/PG 3 Appearance clear colorless to slightly yellowish liquid
Safety 26-36/37/39-45 Risk Codes 10-21/22-34-43
Molecular Structure Molecular Structure of 104-78-9 (3-Diethylaminopropylamine) Hazard Symbols IrritantXi, CorrosiveC
Synonyms

1,3-Propanediamine,N,N-diethyl- (6CI,7CI,8CI,9CI);(3-Diethylaminopropan-1-yl)amine;1-Amino-3-(diethylamino)propane;3-(Diethylamino)-n-propylamine;3-(Diethylamino)propanamine;3-(Diethylamino)propylamine;3-(N,N-Diethylamino)-1-propylamine;3-(N,N-Diethylamino)propylamine;3-Diethylamino-1-propylamine;Diethylaminotrimethylenamine;N,N-Diethyl-1,3-diaminopropane;N,N-Diethyl-1,3-propanediamine;N,N-Diethyl-1,3-propylenediamine;N,N-Diethyltrimethylenediamine;N,N-Ethylpropane-1,3-diamine;N-(3-Aminopropyl)-N,N-diethylamine;N-(3-Aminopropyl)diethylamine;N-(3-Diethylaminopropyl)amine;N-(Diethylaminopropyl)amine;N-Aminopropyl-N,N-diethylamine;N1,N1-Diethylpropane-1,3-diamine;NSC 7776;g-(Diethylamino)propylamine;

Article Data 49

3-Diethylaminopropylamine Synthetic route

20824-58-2

2-(3-diethylaminopropyl)-1H-isoindole-1,3(2H)-dione

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 24h; Reflux;73%
With hydrazine hydrate In ethanol for 3h; Reflux;14%
With hydrazine
5351-04-2

3-diethylaminopropionitrile

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With ethanol; sodium for 3h; Reflux;56%
With sodium-potassium alloy; butan-1-ol
With ethanol; sodium
136918-14-4

phthalimide

104-77-8

3-diethylaminopropyl chloride

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With xylene Hydrolyse des entstandenen N-<3-Diaethylamino-propyl>-phthalimids mit konz.HCl bei Siedetemperatur.;
With xylene Hydrolyse des entstandenen N-<3-Diaethylamino-propyl>-phthalimids mit konz.HCl bei Siedetemperatur.;
5460-29-7

2-(3-bromopropyl)isoindole-1,3-dione

109-89-7

diethylamine

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
Hydrolyse des entstandenen N-<3-Diaethylamino-propyl>-phthalimids mit konz.HCl bei Siedetemperatur.;
(i) KOH, MeOH, (ii) aq. KOH, (heating); Multistep reaction;
Hydrolyse des entstandenen N-<3-Diaethylamino-propyl>-phthalimids mit konz.HCl bei Siedetemperatur.;
5351-04-2

3-diethylaminopropionitrile

A

6050-28-8

bis-(3-diethylamino-propyl)-amine

B

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With sodium-potassium alloy; butan-1-ol
With nickel at 100℃; under 62518.2 Torr; Hydrogenation;
100536-45-6

tetra-N-ethyl-ξ-propenediyldiamine

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With ammonia; nickel at 100℃; under 91938.4 Torr; Hydrogenation;
With ammonia; nickel at 100℃; under 91938.4 Torr; Hydrogenation;
109-89-7

diethylamine

156-87-6

propan-1-ol-3-amine

A

107-11-9

1-amino-2-propene

B

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With thorium dioxide at 270 - 290℃;
503-29-7

azetidine

109-89-7

diethylamine

A

103502-67-6

1-<(3-aminopropyl)aminopropyl>diethylamine

B

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With perchloric acid at 25℃; Rate constant; Thermodynamic data; E(a), ΔS(excit.);
N,N-diethyl-β-alynyne-nitrile

N,N-diethyl-β-alynyne-nitrile

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
5351-04-2

3-diethylaminopropionitrile

Raney nickel

Raney nickel

A

6050-28-8

bis-(3-diethylamino-propyl)-amine

B

104-78-9

diethylaminopropylamine

Conditions
ConditionsYield
Hydrogenation;

3-Diethylaminopropylamine Chemical Properties

Product Name:3-Diethylaminopropylamine
The MF of 3-Diethylaminopropylamine(104-78-9) is C7H18N2.

                        
The MW of 3-Diethylaminopropylamine(104-78-9) is 130.23.
Synonyms:1-(Diethylamino)propylamine-3;1,3-Propanediamine,N,N-diethyl-;3-(N,N-Diethylamino)-1-propylamine;N-(3-Diethylaminopropyl)amine;3-Propanediamine,N,N-diethyl-1;Diethylaminotrimethylenamine;N,N-(Diethylamino)propylamine
EINECS: 203-236-4 
Mol File: 104-78-9.mol
Surface Tension: 30.8 dyne/cm 
Density: 0.84 g/ml
Flash Point: 58.9 °C 
Enthalpy of Vaporization: 40.71 kJ/mol 
Boiling Point: 170.7 °C at 760 mmHg 
Vapour Pressure: 1.45 mmHg at 25°C 
Water Solubility: MISCIBLE
Sensitive: Air Sensitive
BRN: 741879
CAS DataBase Reference: 104-78-9(CAS DataBase Reference)
NIST Chemistry Reference: 104-78-9(NIST)
EPA Substance Registry System: 104-78-9(EPA Substance)

3-Diethylaminopropylamine Uses

The 3-Diethylaminopropylamine(104-78-9) is used as a solvent, extraction agents and organic synthesis intermediates, dyes, pigments, surface active agent.

3-Diethylaminopropylamine Toxicity Data With Reference

1.   

skn-rbt 100 µg/24H open

   AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
2.   

orl-rat LD50:1410 mg/kg

   UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 2/27 ,1967.
3.   

skn-rbt LD50:750 mg/kg

   AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.

3-Diethylaminopropylamine Consensus Reports

Reported in EPA TSCA Inventory.

3-Diethylaminopropylamine Safety Profile

Moderately toxic by ingestion and skin contact. Corrosive to the eyes, skin, and mucous membranes. A sensitizer. See also AMINES. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx.
Safety information of 3-Diethylaminopropylamine(104-78-9):
Hazard Codes: C,Xi
Risk Statements: 10-21/22-34-43
R10:Flammable ;
R21/22:Harmful in contact with skin and if swallowed ;
R34:Causes burns ;
R43:May cause sensitization by skin contact ;
Safety Statements: 26-36/37/39-45
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice ;
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection ;
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) ;
RIDADR: UN 2684 3/PG 3
WGK Germany: 1
RTECS: TX7350000
HazardClass: 3
PackingGroup: III
HS Code: 29212900

3-Diethylaminopropylamine Standards and Recommendations

DOT Classification:  8; Label: Corrosive, Flammable Liquid

3-Diethylaminopropylamine Specification

The 3-Diethylaminopropylamine(104-78-9) is stable but imcompatible with strong oxidizing agents, acids, acid chlorides, carbon dioxide, nitrites, acid anhydrides, nitric oxide.Hazardous decomposition products are nitrogen oxides, carbon monoxide, carbon dioxide, nitrosamines.
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