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4,4'-Dimethoxydiphenylamine

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4,4'-Dimethoxydiphenylamine

EINECS 202-968-1
CAS No. 101-70-2 Density 1.126 g/cm3
Solubility Melting Point 101-102 °C
Formula C14H15NO2 Boiling Point 371.1 °C at 760 mmHg
Molecular Weight 229.30 Flash Point 150.5 °C
Transport Information Appearance silver-grey crystalline solid
Safety 22-36/37/39 Risk Codes 68
Molecular Structure Molecular Structure of 101-70-2 (Benzenamine,4-methoxy-N-(4-methoxyphenyl)-) Hazard Symbols
Synonyms

Diphenylamine,4,4'-dimethoxy- (6CI,7CI,8CI);4-Methoxy-N-(4-methoxyphenyl)benzenamine;Bis(4-methoxyphenyl)amine;Bis(p-anisyl)amine;Bis(p-methoxyphenyl)amine;Di(p-methoxyphenyl)amine;Di-p-anisylamine;Difenam;Fenam M;N,N-Bis(4-methoxyphenyl)amine;N-(4-Methoxyphenyl)-p-anisidine;N-(p-Methoxyphenyl)-p-anisidine;Thermoflex;p,p'-Dimethoxydiphenylamine;

 

4,4'-Dimethoxydiphenylamine Chemical Properties

IUPAC Name: 4-Methoxy-N-(4-methoxyphenyl)aniline
Synonyms: 4,4'-Dimethoxydiphenylamine ; 4-Methoxy-N-(4-methoxyphenyl)aniline ; Benzenamine, 4-methoxy-N-(4-methoxyphenyl)- ; Bis(p-anisyl)amine ; Bis(4-methoxyphenyl)amine ; Bis(p-anisylamine) ; Bis(p-methoxyphenyl)amine ; Di-p-anisylamine  
Product Categories: Diphenylamines (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research
Molecular Structure of bis(4-Methoxyphenyl)amine (CAS NO.101-70-2) :
Molecular Formula of bis(4-Methoxyphenyl)amine (CAS NO.101-70-2) : C14H15NO2
Molecular Weight of bis(4-Methoxyphenyl)amine (CAS NO.101-70-2) : 229.27
CAS NO: 101-70-2
EINECS : 202-968-1
BRN 2214262
Mol File: 101-70-2.mol
Index of Refraction: 1.593
Surface Tension: 40.7 dyne/cm
Density: 1.126 g/cm3
Flash Point: 150.5 °C
Enthalpy of Vaporization: 61.81 kJ/mol
Boiling Point: 371.1 °C at 760 mmHg
Vapour Pressure: 1.06E-05 mmHg at 25°C
Melting point: 101-102°C
Sensitive : Air Sensitive
Stability: Stability Combustible. Incompatible with strong oxidizing agents.
Appearance: Bis(4-Methoxyphenyl)amine (CAS NO.101-70-2) silver-grey crystalline solid .
 

4,4'-Dimethoxydiphenylamine Toxicity Data With Reference

1.    

cyt-ham:lng 30 mg/L

    MUREAV    Mutation Research. 241 (1990),175.
2.    

orl-rat LD50:2470 mg/kg

    KCRZAE    Kauchuk i Rezina. 26 (9)(1967),28.
3.    

orl-mus LD50:2500 mg/kg

    KCRZAE    Kauchuk i Rezina. 26 (9)(1967),28.

4,4'-Dimethoxydiphenylamine Consensus Reports

Reported in EPA TSCA Inventory.

4,4'-Dimethoxydiphenylamine Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.
Risk Statements 68
R68:Possible risk of irreversible effects.
Safety Statements 22-36/37/39
S22:Do not breathe dust. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RTECS DU9085000

4,4'-Dimethoxydiphenylamine Specification

1.General Description :Fine very light gray to silver-gray crystalline solid.
2.Air & Water Reactions: Bis(4-Methoxyphenyl)amine may be sensitive to prolonged exposure to air. Slowly oxidized. Insoluble in water.
3.Reactivity Profile : Bis(4-Methoxyphenyl)amine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
4.Health Hazard : acute/chronic hazards: 4,4'-dimethoxydiphenylamine can produce extremely irritating fumes when exposed to air or fire.

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