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Cas Database

Name	4-Aminobiphenyl	EINECS	202-177-1
CAS No.	92-67-1	Density	1.077 g/cm³
PSA	26.02000	LogP	3.51700
Solubility	842 mg/L at 20–30 °C (quoted, Mercer et al., 1990)	Melting Point	52-54 °C(lit.)
Formula	C₁₂H₁₁N	Boiling Point	302 °C at 760 mmHg
Molecular Weight	169.226	Flash Point	152.2 °C
Transport Information	UN 3077 9/PG 3	Appearance	brownish yellow solid
Safety	53-45-36-26	Risk Codes	45-22-36/37/38-20/21/22
Molecular Structure		Hazard Symbols	T,Xn
Synonyms	4-Biphenylamine(8CI);(1,1'-Biphenyl-4-yl)amine;4-Amino-1,1'-biphenyl;4-Biphenylylamine;4-Phenylaniline;4-Phenylbenzenamine;NSC7660;Xenylamine;p-Aminobiphenyl;p-Biphenylamine;p-Phenylaniline;p-Xenylamine;	Article Data	348

4-Aminobiphenyl Chemical Properties

IUPAC Standard InChIKey: DMVOXQPQNTYEKQ-UHFFFAOYSA-N
Synonyms: 4-adp;4-Aminodiphenyl;4-Aminobifenyl;4-aminobiphenyle;4-Aminodifenil;4-Bifenylamin;Aniline, p-phenyl-;biphenyl-4-ylamine;
The Molecular formula of 4-AMINODIPHENYL(92-67-1): C₁₂H₁₁N
The Molecular Weight of 4-AMINODIPHENYL(92-67-1): 169.22
Molecular Structure :

EINECS: 202-177-1
Melting point: 52-54 °C(lit.)
Boiling point: 191 °C at 15 mm Hg(lit.)
Flash point: >110°C
Appearance: Brownish Yellow Solid
Merck: 13,1235

4-Aminobiphenyl Uses

4-AMINODIPHENYL(92-67-1)is used as dye and pesticide intermediates.

4-Aminobiphenyl Toxicity Data With Reference

1.	mma-sat 2 µg/plate	ENMUDM Environmental Mutagenesis. 5 (Suppl 1)(1983),3.
2.	dnd-esc 30 µmol/L	MUREAV Mutation Research. 89 (1981),95.
3.	msc-hmn:fbr 60 mg/L	MUREAV Mutation Research. 121 (1983),71.
4.	dnd-rat:lvr 30 µmol/L	SinJF# Personal Communication from J.F. Sina, Merck Institute for Therapeutic Research, West Point, PA 19486, to the Editor of RTECS, Cincinnati, OH, on October 26, 1982
5.	dns-mus-orl 200 mg/kg	MUREAV Mutation Research. 125 (1984),291.
6.	orl-rat LD50:500 mg/kg	JIHTAB Journal of Industrial Hygiene and Toxicology. 29 (1947),1.
7.	orl-mus TD:5460 µg/kg	EJCODS European Journal of Cancer and Clinical Oncology. 21 (1985),865.
8.	orl-rat LD50:500 mg/kg	JIHTAB Journal of Industrial Hygiene and Toxicology. 29 (1947),1.
9.	orl-mus LD50:205 mg/kg	EJCODS European Journal of Cancer and Clinical Oncology. 21 (1985),865.
10.	ipr-mus LDLo:250 mg/kg	CBCCT* “Summary Tables of Biological Tests” Na

4-Aminobiphenyl Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 91.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 (1972),p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 (1972),p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 28 (1982),p. 151.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.

4-Aminobiphenyl Safety Profile

Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Human mutation data reported. An irritant. Effects resemble those of benzidine. See also BENZIDINE. Slight to moderate fire hazard when exposed to heat, flames (sparks), or powerful oxidizers. To fight fire, use water spray, mist, dry chemical. When heated to decomposition it emits toxic fumes of NO_x. See also AROMATIC AMINES.
The Hazard Codes of 4-AMINODIPHENYL(92-67-1):

Xn
HazardClass: 6.1(a)
The Risk Statements information of 4-AMINODIPHENYL(92-67-1):
22: Harmful if swallowed
45: May cause cancer
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 4-AMINODIPHENYL(92-67-1):
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
53: Avoid exposure - obtain special instruction before use
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: DU8925000
PackingGroup: I

4-Aminobiphenyl Standards and Recommendations

OSHA PEL: Cancer Suspect Agent
ACGIH TLV: Confirmed Human Carcinogen
DFG MAK: Human Carcinogen

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