- 4-Chlorobenzyl chloride
- 4-CHLOROBENZYL CYANIDE
- 4-Chlorobenzyl isothiocyanate
- 4-Chlorobenzyl mercaptan
- 4-Chlorobenzylmagnesium chloride
- 4-Chlorobenzylamine
- 4-Chlorobenzyl bromide
- 4-Chlorobenzyl alcohol
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Cas Database |
| Name |
4-Chlorobenzyl mercaptan |
EINECS | 228-395-7 |
| CAS No. | 6258-66-8 | Density | 1.2 |
| PSA | 38.80000 | LogP | 2.76980 |
| Solubility | insoluble in water | Melting Point |
19-20 °C(lit.) |
| Formula | C7H7 Cl S | Boiling Point | 125°C 35mm |
| Molecular Weight | 158.652 | Flash Point | 76 ºC |
| Transport Information | UN2810 | Appearance | Clear, colorless liquid. With a stench. |
| Safety | 26-36/37/39 | Risk Codes | R20/21/22 |
| Molecular Structure |
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Hazard Symbols |
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| Synonyms |
a-Toluenethiol, p-chloro-(6CI,7CI,8CI); (4-Chlorophenyl)methanethiol; (p-Chlorophenyl)methanethiol;4-Chloro-a-toluenethiol; 4-Chlorobenzenemethanethiol;4-Chlorobenzyl mercaptan; 4-Chlorobenzylthiol; NSC 108735; NSC 203281;p-Chloro-a-toluenethiol;p-Chlorobenzenemethanethiol; p-Chlorobenzyl mercaptan; p-Chlorobenzylthiol |
Article Data | 24 |
4-Chlorobenzyl mercaptan Synthetic route
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| With pyrrolidine In acetonitrile at 20℃; | 95% |
| Conditions | Yield |
|---|---|
| With hydrosulfide exchange resin In acetonitrile at 25℃; for 0.25h; | 93% |
| With tetraethylammonium iodide; 1-(2-hydroxyethyl)-4,6-diphenylpyridin-2-thione In acetonitrile for 24h; Ambient temperature; | 72% |
| With sodium hydrogensulfide |
- 624731-62-0
S-(4-chlorobenzyl) ethanethioate
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| With methanol; tetra-n-butylammonium cyanide In chloroform at 20℃; for 3h; | 92% |
| Acid hydrolysis; |
- 96185-26-1
1-(2-hydroxyethyl)-4,6-diphenylpyridin-2-thione
A
- 96185-27-2
2,3-dihydro-5,7-diphenyloxazolo(3,2-a)pyridinium iodide
B
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| With 1-chloro-4-(iodomethyl)benzene In benzene at 20℃; for 3h; various alkyl and aryl halogenides; | A n/a B 89% |
- 35424-56-7
1-chloro-4-(iodomethyl)benzene
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| With 1-(2-hydroxyethyl)-4,6-diphenylpyridin-2-thione In benzene at 20℃; for 3h; | 89% |
- 108-24-7
acetic anhydride
- 90732-58-4
2-(4-chlorobenzyl)isothiouronium bromide
A
- 111039-44-2
4-(4-Chloro-benzylsulfanyl)-6-methyl-[1,3,5]triazin-2-ylamine
B
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| In pyridine for 0.5h; Heating; | A 60% B n/a |
- 123-62-6
propionic acid anhydride
- 90732-58-4
2-(4-chlorobenzyl)isothiouronium bromide
A
- 111039-46-4
4-(4-Chloro-benzylsulfanyl)-6-ethyl-[1,3,5]triazin-2-ylamine
B
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| In pyridine for 0.5h; Heating; | A 57% B n/a |
- 28249-27-6
4-chlorobenzyl dimethylcarbamodithioate
- 6258-66-8
(4-chlorophenyl)methanethiol
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
| Conditions | Yield |
|---|---|
| With ethanol Erwaermen des Reaktionsgemisches mit wss. NaOH; |
- 64-17-5
ethanol
- 26504-33-6
dithiocarbonic acid O,S-bis-(4-chloro-benzyl ester)
- 100-63-0
phenylhydrazine
B
- 6258-66-8
(4-chlorophenyl)methanethiol
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