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Name	4-IsopropylAniline	EINECS	202-797-2
CAS No.	99-88-7	Density	0.989
PSA	26.02000	LogP	2.97340
Solubility	insoluble	Melting Point	-63 ºC
Formula	C9H13 N	Boiling Point	226-228 ºC
Molecular Weight	135.209	Flash Point	92 ºC
Transport Information	N/A	Appearance	light brown clear liquid
Safety	S36/37	Risk Codes	R20/21/22
Molecular Structure		Hazard Symbols
Synonyms	Cumidine(6CI,7CI,8CI); 1-Amino-4-isopropylbenzene; 4-(1-Methylethyl)benzenamine;4-(2-Propyl)aniline; 4-Amino-1-isopropylbenzene; 4-Aminocumene;4-Aminoisopropylbenzene; 4-Isopropylaniline; 4-Isopropylbenzenamine;4-Isopropylphenylamine; NSC 7198; [4-(1-Methylethyl)phenyl]amine; p-Cumidine;p-Isopropylaniline; b-(4-Aminophenyl)propane	Article Data	63

4-IsopropylAniline Synthetic route

: 1817-47-6
4-nitrocumene

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With triethylamine In water at 80℃; for 2h; Inert atmosphere; Green chemistry; chemoselective reaction;	99%
With borane-ammonia complex In methanol; water at 49.84℃; for 0.1h; Catalytic behavior;	99%
With nickel; ammonium chloride In water at 80 - 90℃; for 1.5h;	96%

: 16152-51-5
(4-isopropylphenyl)boronic acid

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With copper(I) oxide; ammonium hydroxide; air In methanol at 20℃; for 12h;	88%

: 15887-26-0
1,2-Bis(4-isopropylphenyl)diazene

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With perchloric acid In isopropyl alcohol; acetonitrile at 25℃; for 0.8h; pH=2; Inert atmosphere; Irradiation;	88%

: 920-39-8
isopropylmagnesium bromide

: 540-37-4
p-aminoiodobenzene

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran -78 deg C, 10 min, reflux, 24 h;	87%

: 768-52-5
N-Isopropylaniline

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With aluminum oxide; aluminium trichloride for 0.0583333h; microwave irradiation;	87%

: 586-61-8
2-(4-bromophenyl)propane

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With ammonium hydroxide; L-2-O-methyl-chiro-inositol; copper(II) acetate monohydrate In 1-methyl-pyrrolidin-2-one at 110℃; for 20h;	87%

: 2621-46-7
1-chloro-4-isopropylbenzene

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With ammonium sulfate; bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate at 100 - 110℃; for 12h;	81%

: 63693-65-2
4-isopropylphenylhydrazine

: 99-88-7
4-Isopropylaniline

Conditions

Conditions	Yield
With 4,4'-di-tert-butylbiphenyl; lithium; nickel dichloride In tetrahydrofuran at 20℃; Reduction;	72%

: 98-82-8
Isopropylbenzene

A: 99-88-7
4-Isopropylaniline

B: 5369-16-4
meta-iso-propyl aniline

C: 643-28-7
2-isopropylaniline

Conditions

Conditions	Yield
With tris-(2-chloro-ethyl)-amine; trifluorormethanesulfonic acid; trifluoroacetic acid In chloroform at 25℃; for 5h;	A 37% B 9% C 48%

: 62-53-3
aniline

: 67-63-0
isopropyl alcohol

A: 187737-37-7
propene

B: 99-88-7
4-Isopropylaniline

C: 768-52-5
N-Isopropylaniline

D: 643-28-7
2-isopropylaniline

Conditions

Conditions	Yield
With Ce-Y zeolite at 300℃; Product distribution; var. zeolites, temp., and flow rate;	A n/a B 1.9% C 4% D 10.7%

...Expand

4-IsopropylAniline Chemical Properties

Product Name:4-Isopropylaniline.
The MF of 4-Isopropylaniline(99-88-7) is C₉H₁₃N.

The MW of 4-Isopropylaniline(99-88-7) is 135.21.
Synonyms:4-AMINO-1-ISOPROPYLBENZENE;4-AMINOCUMENE;4-AMINOCUMOL;4-ISOPROPYLANILINE;AKOS BBS-00003562;CUMIDENE;CUMIDINE;P-ISOPROPYLANILINE
EINECS: 202-797-2
Mol File: 99-88-7.mol
MP:-63 °C
FP:198 °F
BP:226-227 °C745 mm Hg(lit.)
Density:0.989 g/mL at 25 °C(lit.)
Refractive index:n20/D 1.543(lit.)
Water Solubility:insoluble
Sensitive:Light Sensitive
Merck:14,2620
BRN:1930544
CAS DataBase Reference:99-88-7(CAS DataBase Reference)
NIST Chemistry Reference:99-88-7(NIST)

4-IsopropylAniline Uses

The 4-Isopropylaniline(99-88-7) is used as an intermediate herbicide isoproturon,medicine and pesticide intermediates.

4-IsopropylAniline Toxicity Data With Reference

RTECS#: CAS# 99-88-7: None listed
LD50/LC50: RTECS: Not available.
Carcinogenicity: 4-Isopropylaniline - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.

4-IsopropylAniline Safety Profile

Safety information of 4-Isopropylaniline(99-88-7):
Hazard Codes:

Xi,Xn
Risk Statements:36/37/38-20/21/22
R36/37/38:Irritating to eyes, respiratory system and skin ;
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed ;
Safety Statements:26-36/37
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice ;
S36/37:Wear suitable protective clothing and gloves ;
WGK Germany:2
Hazard Note:Irritant
HS Code:29214980

4-IsopropylAniline Specification

It is air sensitive and light sensitive.Incompatibilities with strong oxidizing agents, strong acids.Hazardous decomposition products are carbon monoxide, oxides of nitrogen, carbon dioxide.

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