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Cas Database |
| Name |
4-Vinylbenzyl chloride |
EINECS | 216-471-2 |
| CAS No. | 1592-20-7 | Density | 1.066 g/cm3 |
| PSA | 0.00000 | LogP | 3.06840 |
| Solubility | Insoluble in water | Melting Point |
N/A |
| Formula | C9H9Cl | Boiling Point | 228.9 °C at 760 mmHg |
| Molecular Weight | 152.623 | Flash Point | 90.4 °C |
| Transport Information | UN 3265 8/PG 3 | Appearance | clear yellow liquid |
| Safety | 26-36/37/39-45 | Risk Codes | 34-43-21/22 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
Styrene,p-(chloromethyl)- (6CI,7CI,8CI);1-(Chloromethyl)-4-vinylbenzene;4-(Chloromethyl)styrene;CMS 14;p-(Chloromethyl)styrene;p-Vinylbenzyl chloride; |
Article Data | 18 |
4-Vinylbenzyl chloride Synthetic route
- 35793-35-2
p-chloromethyl-α-bromoethylbenzene
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| With 18-crown-6 ether; potassium hydroxide In toluene at 40℃; for 4h; Reagent/catalyst; Temperature; Solvent; | 95% |
| Conditions | Yield |
|---|---|
| With oxalyl dichloride; Tropone In dichloromethane at 20℃; for 0.25h; Inert atmosphere; | 84% |
- 53459-40-8
1-(2-chloroethyl)-4-(chloromethyl)benzene
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| With 4-tert-Butylcatechol; sodium t-butanolate In tetrahydrofuran at 30℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere; | 83% |
- 24249-98-7
p-chloromethyl-2-bromoethylbenzene
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| With potassium hydroxide; tetrabutylammomium bromide at 30℃; for 4h; different reagents, solvents and reaction times; | 77% |
| With tetrabutylammomium bromide; potassium hydroxide In tert-butyl alcohol at 30℃; for 4h; | 50.1% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; potassium chloride; tetrabutyl-ammonium chloride In fluorobenzene; water at 20℃; Irradiation; Green chemistry; | 68% |
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| at 500 - 650℃; | 60% |
| Conditions | Yield |
|---|---|
| With carbon disulfide; zinc(II) chloride at 40℃; for 5h; Reflux; | 13% |
| Conditions | Yield |
|---|---|
| (i) NBS, (PhCO)2O2, (ii) (heating), benzene-1,4-diol; Multistep reaction; |
- 76297-21-7
1-(4-chloromethylphenyl)ethanol
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| With potassium hydrogensulfate; 4-tert-Butylcatechol at 210℃; |
- 622-97-9
1-ethenyl-4-methylbenzene
A
- 42107-37-9
α-chloro-p-methylstyrene
B
- 1592-20-7
4-Vinylbenzyl chloride
| Conditions | Yield |
|---|---|
| With chlorine In water at 560℃; for 0.000222222h; Product distribution; gas phase reaction, oth. isomers; |
4-Vinylbenzyl chloride Chemical Properties
IUPAC Name: 1-(Chloromethyl)-4-ethenylbenzene
Synonyms of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): EINECS 216-471-2 ; 1-(Chloromethyl)-4-vinylbenzene
CAS NO: 1592-20-7
Molecular Formula: C9H9Cl
Molecular Weight: 152.6208
Molecular Structure:
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ProductCategories: Intermediates of Dyes and Pigments
Index of Refraction: 1.57
Molar Refractivity: 46.94 cm3
Molar Volume: 143 cm3
Surface Tension: 34.7 dyne/cm
Density of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): 1.066 g/cm3
Flash Point: 90.4 °C
Enthalpy of Vaporization: 44.66 kJ/mol
Boiling Point: 228.9 °C at 760 mmHg
Vapour Pressure: 0.108 mmHg at 25°C
4-Vinylbenzyl chloride Safety Profile
Hazard Codes of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): 
C
Risk Statements: 34-43-21/22
R34: Causes burns.
R43: May cause sensitization by skin contact.
R21/22: Harmful in contact with skin and if swallowed.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3265 8/PG 3
WGK Germany: 3
F: 8-19
HazardClass: 8
PackingGroup: III
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