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Acetoxyphenylmercury

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Acetoxyphenylmercury

EINECS 200-532-5
Annex I Index No: 080-011-00-5
CAS No. 62-38-4 Density 2,4 g/cm3
PSA 26.30000 LogP 0.87250
Solubility slight

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Toxic if inhaled, swallowed, or absorbed through the skin. Experimentalteratogen. Corrosive - skin or eye contact may cause bu
Melting Point 148-151 °C(lit.)

Formula C8H8 Hg O2 Boiling Point N/A
Molecular Weight 336.74 Flash Point N/A
Transport Information N/A Appearance white crystalline powder
Safety Poison by ingestion, intravenous, intraperitoneal, subcutaneous, and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits toxic fumes of Hg. Risk Codes R25;R34;R48/24/25;R50/53;
Molecular Structure Molecular Structure of 62-38-4 (PHENYLMERCURIC ACETATE) Hazard Symbols Toxic by ingestion, inhalation, and skin absorption; strong irritant.
Synonyms

Mercury,(acetato)phenyl- (8CI); Mercury, (acetato-O)phenyl-; Phenylmercury acetate(6CI); (Acetato-O)phenylmercury; Acetatophenylmercury; Acetic acid,phenylmercury deriv.; Acetoxyphenylmercury; Agrosan; Agrosan D; Algimycin 200;Anticon; Antimucin WBR; Antimucin WDR; Benzene, (acetoxymercurio)-; Bufen;Bufen 30; Ceresol; Contra Creme; Femma; Fungicide R; Fungitox OR; Hexasan;Hexasan (fungicide); Intercide 60; Intercide PMA 18; Liquiphene; Lorophyn;Meracen; Mercron; Mercuriphenyl acetate; Mercuron; Mergal A 25; Mersolite 8;Mersolite D; NSC 35670; NSC 61321; Neantina; Norforms; Nuodex PMA 18;Nylmerate; PMA; PMA (fungicide); PMA 220; PMAC; PMAS; Panomatic; Parasan;Parasan (bactericide); Phenylmercuric acetate; Phix; Programin; Quicksan;Ruberon; Samtol; Sanitized SPG; Sanmicron; Scutl; Seed Dressing R; Seedtox;Setrete; Spruce Seal; Tag; Tag 331; Tag Fungicide; Tag HL 331; Trigosan; Troysan30; Troysan PMA 30; Verdasan; Volpar; Zaprawa Nasienna R; Ziarnik

Article Data 19

Acetoxyphenylmercury Chemical Properties

Empirical Formula: C8H8HgO2
Molecular Weight: 336.7379
EINECS: 200-532-5
Melting point: 148-151 °C(lit.)
Storage temp: Approx 4 °C
Appearance: White crystalline powder
Stable: Stable. Incompatible with strong oxidizing agents.
Product categories ofAcetoxyphenylmercury (CAS NO.62-38-4): Organometallics
Structure of Acetoxyphenylmercury (CAS NO.62-38-4):
               
IUPAC Name: Acetyloxy(phenyl)mercury
Canonical SMILES: CC(=O)O[Hg]C1=CC=CC=C1
InChI: InChI=1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
InChIKey: XEBWQGVWTUSTLN-UHFFFAOYSA-M
 

Acetoxyphenylmercury Uses

 Acetoxyphenylmercury (CAS NO.62-38-4) has been used as an herbicide and fungicide.

Acetoxyphenylmercury Production

 Acetoxyphenylmercury (CAS NO.62-38-4) can be obtained from synthesis of Benzene, acetic acid and Mercuric oxide , and then by post-processing.

Acetoxyphenylmercury Toxicity Data With Reference

1.    

dnr-esc 2 mmol/L

    MJDHDW    Mukogawa Joshi Daigaku Kiyo, Yakugaku Hen. Bulletin of Mukogawa Womens College, Food Science Series. 28 (1980),F39.
2.    

sce-ham:lym 30 mg/L

    DBABEF    Doga Bilim Dergisi, Seri A2: Biyoloji. Natural Science Journal, Series A2. 8 (1984),105.
3.    

orl-rat LD50:41 mg/kg

    JACTDZ    Journal of the American College of Toxicology. 1 (1992),175.
4.    

orl-mus LD50:13,250 µg/kg

    YAKUD5    Gekkan Yakuji. Pharmaceuticals Monthly. 22 (1980),291.
5.    

ipr-mus LD50:13 mg/kg

    AMSVAZ    Acta Medica Scandinavica. 143 (1952),365.
6.    

scu-mus LD50:12 mg/kg

    TOIZAG    Toho Igakkai Zasshi. Journal of Medical Society of Toho University. 9 (1962),101.
7.    

ivn-mus LD50:18 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00921 .
8.    

orl-ckn LD50:60 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 2 (1960),344.
9.    

orl-qal LD50:71 mg/kg

    AXVMAW    Archiv fuer Experimentelle Veterinaermedizin. 34 (1980),383.
10.    

ipr-uns LD50:10 

Acetoxyphenylmercury Consensus Reports

IARC Cancer Review: Group 2B, Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 (1993),p. 239.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Mercury and its compounds are on the Community Right-To-Know List.

Acetoxyphenylmercury Safety Profile

Poison by ingestion, intravenous, intraperitoneal, subcutaneous, and possibly other routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits toxic fumes of Hg.
 

Hazard Codes: ToxicTDangerousN
Risk Statements:
R24:Toxic in contact with skin. 
R25 :Toxic if swallowed. 
R34:Causes burns. 
R48:Danger of serious damage to health by prolonged exposure. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:
S23:Do not breathe vapour. 
S24:Avoid contact with skin. 
S25:Avoid contact with eyes. 
S37:Wear suitable gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.

Acetoxyphenylmercury Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)
DOT Classification:  6.1; Label: Poison

Acetoxyphenylmercury Specification

 Acetoxyphenylmercury ,its cas register number is 62-38-4. It also can be called Mercury, (acetato-O)phenyl- ; Phenylmercuric acetate and (Acetato-O)phenylmercury . It may react with strong oxidizing agents and is mixed with organic solvent for the purpose of application.

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