- Ammonium 1-pyrrolidinedithiocarbamate
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- Ammonium chloride((ND4)Cl) (7CI,8CI,9CI)
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Cas Database |
| Name |
Ammonium 1-pyrrolidinedithiocarbamate |
EINECS | 225-834-4 |
| CAS No. | 5108-96-3 | Density | 1.117 (estimate) |
| PSA | 77.37000 | LogP | 1.55870 |
| Solubility | water: 50 g/L (20 °C) | Melting Point |
150-155 °C |
| Formula | C5H9NS2.NH3 | Boiling Point | 199.7 °C at 760 mmHg |
| Molecular Weight | 164.296 | Flash Point | 74.6 °C |
| Transport Information | N/A | Appearance | pale yellow crystalline solid |
| Safety | 26-36-37/39 | Risk Codes | 36/37/38-22 |
| Molecular Structure |
|
Hazard Symbols |
 Xi, Xn
|
| Synonyms |
1-Pyrrolidinecarbodithioicacid, ammonium salt (8CI,9CI);APDC;Ammonium N,N-tetramethylenedithiocarbamate;Ammonium pyrrolidine-1-dithiocarbamate;Ammonium pyrrolidine-N-dithiocarbamate;Ammonium pyrrolidinedithiocarboxylate; |
Article Data | 3 |
Ammonium 1-pyrrolidinedithiocarbamate Synthetic route
| Conditions | Yield |
|---|---|
| With ammonium hydroxide In diethyl ether for 1h; | 85% |
| With ammonium hydroxide In ethanol | |
| With ammonia |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
- 78134-74-4
(benzoylaminomethyl)triethylammonium chloride
| Conditions | Yield |
|---|---|
| With triethylamine In water at 20℃; for 1h; | 95.7% |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
- 56893-25-5
methyl 4-(2-bromoacetyl)benzoate
- 1593781-46-4
methyl 4-(2-((pyrrolidine-1-carbonothioyl)thio)acetyl)benzoate
| Conditions | Yield |
|---|---|
| In acetone at 20℃; for 8h; | 90.1% |
| In acetone at 20℃; for 8h; | 90.1% |
| In acetone at 20℃; for 1.5h; | 83% |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
| Conditions | Yield |
|---|---|
| In water at 20℃; for 0.166667h; | 89.6% |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
| Conditions | Yield |
|---|---|
| In ethanol at 24.84℃; for 6h; | 89% |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
- 77597-29-6
p-nitrobenzyl 3-<(3-mesyloxypropyl)thio>-7-oxo-4-thia-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylate
- 77597-31-0
p-nitrobenzyl 3-<<3-<(1-pyrrolidinylcarbothioyl)thio>propyl>thio>-7-oxo-4-thia-1-azabicyclo<3.2.0>hept-2-ene-2-carboxylate
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide for 1h; Ambient temperature; | 88% |
- 14647-25-7, 83095-83-4
[Pt(dppe)Cl2]
- 5108-96-3
ammonium tetramethylenedithiocarbamate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; | 88% |
- 5108-96-3
ammonium tetramethylenedithiocarbamate
| Conditions | Yield |
|---|---|
| In ethanol at 24.84℃; for 6h; | 88% |
| Conditions | Yield |
|---|---|
| Stage #1: C19H18ClN3O2Pt With silver(I) hexafluorophosphate In 2-methoxy-ethanol for 5h; Darkness; Stage #2: ammonium tetramethylenedithiocarbamate With acetonitrile for 0.5h; Further stages; | 87.9% |
- 54258-41-2
1,10-phenanthroline-5-amine
- 5108-96-3
ammonium tetramethylenedithiocarbamate
| Conditions | Yield |
|---|---|
| In methanol at 20℃; for 0.166667h; | 86.5% |
Ammonium 1-pyrrolidinedithiocarbamate Chemical Properties
IUPAC Name: Azane; pyrrolidine-1-carbodithioic acid
Systematic of 1-Pyrrolidinecarbodithioicacid, ammonium salt (1:1) (CAS NO.5108-96-3): AI3-36577 ; Ammonium 1-pyrrolidinecarbodithioate ; Ammonium 1-pyrrolidinedithiocarboxylate ; Ammonium 1-pyrrolidinyldithiocarbamate ; Ammonium pyrrolidyldithiocarbamate ; Ammonium tetramethylenedithiocarbamate ; EINECS 225-834-4 ; NSC 298194 ; 1-Pyrrolidinecarbodithioic acid, ammonium salt
CAS NO: 5108-96-3
Molecular Formula of 1-Pyrrolidinecarbodithioicacid, ammonium salt (1:1) (CAS NO.5108-96-3): C5H12N2S2
Molecular Weight: 164.2922
Molecular Structure:
.png)
Melting Point: 153-155 °C
H bond acceptors: 1
Polar Surface Area: 60.63 Å2
Flash Point of 1-Pyrrolidinecarbodithioicacid, ammonium salt (1:1) (CAS NO.5108-96-3): 74.6 °C
Enthalpy of Vaporization: 43.59 kJ/mol
Boiling Point: 199.7 °C at 760 mmHg
Vapour Pressure: 0.337 mmHg at 25°C
Ammonium 1-pyrrolidinedithiocarbamate Safety Profile
Hazard Codes: 
Xi,
Xn
Risk Statements: 36/37/38-22
R36/37/38: Irritating to eyes, respiratory system and skin.
R22: Harmful if swallowed.
Safety Statements: 26-36-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
S37/39: Wear suitable gloves and eye/face protection.
WGK Germany: 3
F: 3
HS Code: 29339990
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