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Ammonium iron(III) oxalate trihydrate

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Name

Ammonium iron(III) oxalate trihydrate

EINECS 220-952-2
CAS No. 13268-42-3 Density 1.78 g/cm3

PSA 188.21000 LogP -6.84680
Solubility Very soluble in water. Insoluble in alcohol Melting Point 161°C (rough estimate)
Formula C2H2O4·1/3Fe·H3N·H2O Boiling Point 365.1oC at 760mmHg
Molecular Weight 322.009 Flash Point 188.8oC
Transport Information 26-27-36/37/39-45-25-24/25 Appearance yellow-green crystals
Safety 26-27-36/37/39-45-25-24/25 Risk Codes 21/22-34
Molecular Structure Molecular Structure of 13268-42-3 (Ferric ammonium oxalate trihydrate) Hazard Symbols CorrosiveC,HarmfulXn
Synonyms

Ethanedioicacid, ammonium iron(3+) salt (3:3:1), trihydrate (9CI);Oxalic acid, ammoniumiron(3+) salt (3:3:1), trihydrate (8CI);Ammonium iron oxalate,(NH4)3Fe(C2O4)3, trihydrate;Iron ammonium oxalate, (NH4)3Fe(C2O4)3, trihydrate;

 

Ammonium iron(III) oxalate trihydrate Synthetic route

1113-38-8

ammonium oxalate

13268-42-3

ammonium iron(II) oxalate*3H2O

Conditions
ConditionsYield
With carbonic-acid; iron(II) oxalate

ammonium oxalate

15843-42-2

iron(II) oxalate

13268-42-3

ammonium iron(II) oxalate*3H2O

Conditions
ConditionsYield
in CO2 stream;
in CO2 stream;

Ammonium iron(III) oxalate trihydrate Specification

The Ammonium iron(III) oxalate trihydrate, with the CAS registry number 13268-42-3, is also known as Ammonium iron(III) oxalate trihydrate trihydrate. It belongs to the product category of Industrial/Fine Chemicals. Its EINECS registry number is 220-952-2. This chemical's molecular formula is C2H2O4·1/3Fe·H3N·H2O and molecular weight is 142.69. What's more, its systematic name is called Ammonium hydrogen ethanedioate - iron hydrate (3:3:1:3). It should be stored in a cool, dry and well-ventilated place. This chemical can be prepared by Fe2(SO4)3, BaC2O4 and (NH4)2C2O4.

Physical properties about Ammonium iron(III) oxalate trihydrate are: (1)#H bond acceptors: 18; (2)#H bond donors: 21; (3)#Freely Rotating Bonds: 3; (4)Polar Surface Area: 226.98 Å2

When you are dealing with this chemical, you should be very careful. This chemical may destroy living tissue on contact and may cause burns. It is irritating to respiratory system. Therefore, you should keep container tightly closed and you can not breathe the gas/fumes/vapour/spray. You should avoid contacting with skin and eyes and wear suitable protective clothing, gloves and eye/face protection. In case of contacting with eyes, you must rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: [Fe].O=C(O)C([O-])=O.[O-]C(=O)C(=O)O.[O-]C(=O)C(=O)O.O.O.O.[NH4+].[NH4+].[NH4+]
(2) InChI: InChI=1S/3C2H2O4.Fe.3H3N.3H2O/c3*3-1(4)2(5)6;;;;;;;/h3*(H,3,4)(H,5,6);;3*1H3;3*1H2
(3) InChIKey: XLDOWRCPANHVAW-UHFFFAOYSA-N

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