Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Antimony(V) chloride

Related Products

Hot Products

Name

Antimony(V) chloride

EINECS 231-601-8
CAS No. 7647-18-9 Density 2.36 g/mL at 25oC(lit.)
PSA 0.00000 LogP 3.44750
Solubility decomposes

Stability

    Stable, but reacts with moisture and water. Releases highlytoxic fumes if involved in a fire.

Toxicology

    Harmful if swallowed or inhaled and in contact with skin.Corrosive - causes seve
Melting Point 2.8 °C(lit.)

Formula Cl5Sb Boiling Point 92 °C30 mm Hg(lit.)
Molecular Weight 299.015 Flash Point 79°C/22mm
Transport Information N/A Appearance colourless to light yellow oily liquid
Safety Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE. When heated to decomposition it emits very toxic fumes of Cl and Sb. Risk Codes 34-51/53-40-23/24/25-14-62-48/20-63
Molecular Structure Molecular Structure of 7647-18-9 (ANTIMONY(V) CHLORIDE) Hazard Symbols Corrosive, fumes in moist air, reacts strongly with organics. TLV: 0.5 mg(Sb)/m3.
Synonyms

Antimonypentachloride; Antimony pentachloride (SbCl5); Antimony perchloride;Antimony(V) chloride; Pentachloroantimony

Article Data 92

Antimony(V) chloride Synthetic route

25362-97-4

SbCl5*SO3

A

7791-27-7

pyrosulfuryl chloride

B

2SbCl4(1+)*SO4(2-)=(SbCl4)2SO4

C

7647-18-9

antimonypentachloride

D

7446-11-9

sulfur trioxide

Conditions
ConditionsYield
70°C in vac.;A n/a
B n/a
C n/a
D 95%
10025-91-9

antimony(III) chloride

2696-92-6

nitrosylchloride

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In melt Reaction of SbCl3 melt with NOCl to give SbCl5;80%
With chlorine In melt Reaction of SbCl3 melt with a mixt. of NOCl and Cl2 to give SbCl5;

silver(I) fluoride

A

13709-35-8

disulfur difluoride

B

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With sulfur with melted Ag2F2 at 500°C; gaseous S2F2 formed;A 48.9%
B n/a
With sulfur with melted Ag2F2 at 600°C; gaseous S2F2 formed;A 40.6%
B n/a
With sulfur with melted Ag2F2 at 140-400°C; gaseous S2F2 formed;A 65-67
B n/a
With sulfur with melted Ag2F2; geseous S2F2 formed;
With S with melted Ag2F2; geseous S2F2 formed;
7440-36-0

antimony

A

7647-18-9

antimonypentachloride

B

10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With chlorine with dry Cl2; refluxing over Sb; distn.;
With hydrogenchloride; dihydrogen peroxide In not given powdered Sb reacts with HCl soln. containing H2O2;
With Cl2 with dry Cl2; refluxing over Sb; distn.;
In not given
7440-36-0

antimony

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine heating; distillation;
With chlorine moderatly heating with dry Cl2; fire phonomenon;
With Cl2 heating; distillation;
7440-36-0

antimony

A

antimony(III) sulfide

B

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With thionyl chloride byproducts: SO2, S2Cl2; SbCl3 and Sb2O3 formed in cold with excess of pwdered Sb; Sbl5 formed wth excess of SOCl2 in a sealed tube;
7440-36-0

antimony

7791-23-3

selenium oxychloride

A

7647-18-9

antimonypentachloride

B

10025-91-9

antimony(III) chloride

C

10025-68-0

diselenium dichloride

Conditions
ConditionsYield
with excess of SeOCl2;A 0%
B n/a
C n/a
7440-36-0

antimony

7722-84-1

dihydrogen peroxide

A

7647-18-9

antimonypentachloride

B

10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With hydrogenchloride In water
With HCl In water
7783-70-2

antimony pentafluoride

10241-05-1

molybdenum(V) chloride

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
over 100 °C; molibdenum fluoride forming as by-product;
over 100 °C; molibdenum fluoride forming as by-product;
10025-91-9

antimony(III) chloride

A

7440-36-0

antimony

B

antimonic acid

C

7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With nitric acid In hydrogenchlorideA 0%
B n/a
C n/a
In hydrogenchloride

Antimony(V) chloride Chemical Properties

IUPAC Name: Pentachloro-λ5-stibane
Synonyms: Antimony pentachloride ; Antimony, pentachloro- ; Pentachlorostiborane ; Antimony (V) chloride
Product Categories: Intermediates of Dyes and Pigments;Inorganics;Antimony Salts;Metal and Ceramic Science;Salts
CAS NO: 7647-18-9
Molecular Formula of Antimony(V) chloride (CAS NO.7647-18-9) : Cl5Sb
Molecular Weight of Antimony(V) chloride (CAS NO.7647-18-9) : 299.02
Molecular Structure of Antimony(V) chloride (CAS NO.7647-18-9) :
EINECS: 231-601-8
Mol File: 7647-18-9.mol
Merck : 14,695
Melting point: 2.8 °C(lit.)
Boiling Point: 92 °C30 mm Hg(lit.)
Flash Point: 79°C/22mm
Density 2.36 g/mL at 25 °C(lit.)
Vapor density >10.2 (vs air)
Vapor pressure 0.13 psi ( 55 °C)
Refractive index 1.601
Sensitive Moisture Sensitive
Stability: Stable, but reacts with moisture and water. Releases highly toxic fumes if involved in a fire.
Appearance:colourless to light yellow oily liquid

Antimony(V) chloride Uses

 Antimony(V) chloride (CAS NO.7647-18-9) is used for high-purity analytical reagents, catalysts, and also for preparation of high purity antimony.

Antimony(V) chloride Production

 Antimony(V) chloride (CAS NO.7647-18-9) is prepared by passing chlorine gas into molten antimony trichloride:
SbCl3 + Cl2 → SbCl5 
 

Antimony(V) chloride Toxicity Data With Reference

1.    

mrc-bcs 30 µL/disc

    MUREAV    Mutation Research. 77 (1980),109.
2.    

orl-rat LD50:1115 mg/kg

    HYSAAV    Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 29 (12)(1964),16.
3.    

orl-gpg LD50:900 mg/kg

    HYSAAV    Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 29 (12)(1964),16.

Antimony(V) chloride Consensus Reports

Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List.

Antimony(V) chloride Safety Profile

Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE. When heated to decomposition it emits very toxic fumes of Cl and Sb.
Hazard Codes ToxicT,DangerousN,CorrosiveC
Risk Statements 34-51/53-40-23/24/25-14
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R14 :Reacts violently with water. 
R34:Causes burns. 
R40:Limited evidence of a carcinogenic effect. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 26-45-61-36/37/39-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S23:Do not breathe vapour.
RIDADR UN 1731 8/PG 3
WGK Germany 2
RTECS CC5075000
F 10
HazardClass 8
PackingGroup II

Antimony(V) chloride Standards and Recommendations

OSHA PEL: TWA 500 µg(Sb)/m3
ACGIH TLV: TWA 0.5 mg(Sb)/m3
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3
DOT Classification:  8; Label: Corrosive

Antimony(V) chloride Specification

1.General Description :A reddish-yellow fuming liquid with a pungent odor. Fumes are irritating to the eyes and mucous membranes. Solidifies at 37°F. Corrosive to metals and tissue. Used to make other chemicals, and in chemical analysis.
2.Air & Water Reactions: Fumes in air to form hydrochloric acid. Reacts with water to yield heat and antimony pentaoxide (Sb2O5) and hydrochloric acid 3.Reactivity Profile: Acidic salts, such as Antimony pentachloride , are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
4.Health Hazard :Inhalation causes irritation of nose and throat. Contact of liquid with eyes or skin causes severe burns. Ingestion causes vomiting and severe burns of mouth and stomach. Overexposure by any route can cause bloody stools, slow pulse, low blood pressure, coma, convulsions, cardiac arrest.
5.Fire Hazard :Behavior in Fire: Irritating fumes of hydrogen chloride given off when water or foam is used to extinguish adjacent fire.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 7647-18-9