Hot Products

Basic Information

Post buying leads

Suppliers

Cas Database

Name	Benzoylformic acid	EINECS	210-278-7
CAS No.	611-73-4	Density	1.298 g/cm³
PSA	54.37000	LogP	0.95390
Solubility	methanol: 0.1 g/mL, clear	Melting Point	60-69 °C
Formula	C₈H₆O₃	Boiling Point	258.6 °C at 760 mmHg
Molecular Weight	150.134	Flash Point	124.4 °C
Transport Information	N/A	Appearance	white to light yellow adhering crystals
Safety	26-28-36-28A-24-22	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Glyoxylicacid, phenyl- (6CI,7CI,8CI);2-Oxo-2-phenylacetic acid;2-Oxo-2-phenylethanoicacid;Benzoylformic acid;CAA 0869;Formic acid, benzoyl-;LFC 1849;NSC 28293;Oxophenylacetic acid;Phenylgloxylic acid;Phenylglyoxylic acid;Phenyloxoacetic acid;a-Ketophenylacetic acid;a-Oxobenzeneacetic acid;	Article Data	360

Benzoylformic acid Synthetic route

: 15206-55-0
methyl 2-oxo-2-phenylacetate

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With water; sodium hydroxide	100%
With water; sodium hydroxide In dichloromethane	100%
With water; sodium hydroxide at 20℃; for 2h;	99.2%

: 7332-98-1
tert-butyl phenylglyoxylate

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane at 20℃;	100%
With trifluoroacetic acid at 0℃; for 1h;	57%
With trifluoroacetic acid at 0℃; for 5h;

: 94-41-7
benzalacetophenone

A: 611-73-4
Benzoylformic acid

B: 65-85-0
benzoic acid

Conditions

Conditions	Yield
With methyl 3,5-bis((1H-1,2,4-triazol-1-yl)methyl)benzoate; oxygen; sodium acetate; nickel dibromide at 120℃; under 760.051 - 912.061 Torr; for 48h; chemoselective reaction;	A 91% B 99%
Multi-step reaction with 2 steps 1: sodium hydrogencarbonate; ruthenium trichloride; potassium peroxymonosulfate / acetonitrile; water; ethyl acetate / 0.3 h 2: iron(II) perchlorate hexahydrate; tetramethylammonium hydroxide pentahydrate / acetonitrile; water / 12 h / Inert atmosphere View Scheme

: 611-71-2, 611-72-3, 17199-29-0, 90-64-2
MANDELIC ACID

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With sodium bromate In acetonitrile for 52h; Heating;	98%
With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine In dichloromethane at -60 - 20℃; Swern oxidation;	96%
With oxalyl dichloride; methyl dodecyl sulfoxide; triethylamine In dichloromethane at -60 - 20℃; Swern oxidation;	96%

: 1352131-39-5
5-hydroxy-N,N',5-triphenylimidazolidine-2,4-dione

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With water; sodium hydroxide In methanol at 20 - 50℃; for 1h;	98%

: 825-52-5
2-(hydroxyimino)-2-phenylacetonitrile

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With sulfuric acid at 100 - 120℃; for 5h;	96.6%

: 93-56-1
phenylethane 1,2-diol

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; iron(III) chloride; thymidyl acetic acid In decane; acetonitrile at 80℃; for 6h;	96%
With Oxone; 2-Iodobenzoic acid In water; acetonitrile at 70℃; for 6h;	94%
With sodium tetrahydroborate; 1% Pd/C; water; potassium hydroxide In methanol at 20℃; for 15h; In air;	91%
With potassium permanganate; acetic acid; Tris(3,6-dioxaheptyl)amine In dichloromethane for 4h; Ambient temperature;	71%
aqua(2,2'-bipyridine)(2,2':6',2''-terpyridine)ruthenium(II)(2+) In phosphate buffer for 6h; pH=7.2; Electrolysis;	47%

: 2425-28-7
2-Bromo-1-phenylethanol

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With tetramethoxytitanium; β-Propiolactone at 60℃; for 2h; Temperature;	96%
Multi-step reaction with 5 steps 1.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C 2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C 3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C 4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C 5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h 5.2: 5 h / 25 - 90 °C View Scheme

Yield

With tetramethoxytitanium; β-Propiolactone at 60℃; for 2h; Temperature;

96%

Multi-step reaction with 5 steps
1.1: hydrogen bromide; dihydrogen peroxide / water / 4.5 h / 25 - 90 °C
2.1: toluene-4-sulfonic acid; benzene / water / 36 h / 85 °C
3.1: tetrabutylammomium bromide; sodium ethanolate / water / 23 h / 105 °C
4.1: oxalic acid / dichloromethane; water / 5 h / 25 °C
5.1: tetrabutylammomium bromide; hydrogen bromide / water / 0.02 h
5.2: 5 h / 25 - 90 °C
View Scheme

: 2-hydroxy-4-methyl-2-phenylmorpholin-3-one

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With hydrogenchloride for 2h; Heating;	94%

: 611-71-2
(R)-Mandelic Acid

: 611-73-4
Benzoylformic acid

Conditions

Conditions	Yield
With phosphotungstic acid; ferric nitrate at 55 - 60℃; for 0.166667h;	93%
With D-lactate oxidase from Gluconobacter oxydans 621H; oxygen; catalase In aq. buffer at 30℃; pH=7.4; Reagent/catalyst; Enzymatic reaction;
With NAD at 30℃; for 48h; pH=9.5; Kinetics; Reagent/catalyst; Temperature; pH-value; Enzymatic reaction;

Benzoylformic acid Chemical Properties

The molecular formula of Benzoylformic acid(611-73-4) is and its formula weight is .
The density of Benzoylformic acid(611-73-4) is 1.38 and it has a melting point of 62-65 °C(lit.). The boiling point is 84 °C0.1 mm Hg. Its flash point is 147-151°C/12mm.
The chemical synonyms of Benzoylformic acid(611-73-4) are PHENYLGLYOXYLIC ACID;OXO(PHENYL)ACETIC ACID;RARECHEM AL BO 0070;2-Oxo-2-phenylacetic acid;alpha-Ketophenylacetic acid;alpha-ketophenylaceticacid;alpha-oxo-benzeneaceticaci;alpha-oxobenzeneaceticacid
The molecular structure of Benzoylformic acid(611-73-4):

Benzoylformic acid Toxicity Data With Reference

ivn-mus LD50:180 mg/kg

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04110 .

Benzoylformic acid Safety Profile

A poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-28-36-28A-24-22
WGK Germany 3
RTECS DA1480000
HS Code 29183000

Benzoylformic acid Specification

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, strong oxidants.
Incompatibilities with Other Materials Strong oxidizing agents, strong reducing agents, strong acids, strong bases.
Hazardous Decomposition Products Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization Has not been reported.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 611-73-4