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Name |
Bis(2-dimethylaminoethyl) ether |
EINECS | 221-220-5 |
CAS No. | 3033-62-3 | Density | 0.883 g/cm3 |
PSA | 15.71000 | LogP | 0.12620 |
Solubility | Soluble | Melting Point |
N/A |
Formula | C8H20N2O | Boiling Point | 194.8 °C at 760 mmHg |
Molecular Weight | 160.26 | Flash Point | 46.2 °C |
Transport Information | UN 2927 6.1/PG 2 | Appearance | A clear or yellow liquid |
Safety | 26-36/37/39-45 | Risk Codes | 20-22-24-34 |
Molecular Structure | Hazard Symbols | T | |
Synonyms |
Ethylamine,2,2'-oxybis[N,N-dimethyl- (6CI,7CI,8CI);1,5-Bis(dimethylamino)-3-oxapentane;2,2'-Oxybis[N,N-dimethylethanamine];2,2'-Oxybis[N,N-dimethylethylamine];A133;A 99 (amine);BL 19;Bis(dimethylaminoethyl) ether;Bis[2-(dimethylamino)ethyl] ether;Dabco BL 11;Dabco BL 19;Dabco BL 19I;ET33B;Jeffcat ZF 20;Jeffcat ZM 20;Kaolizer 12P;MinicoTMDA;N,N,N',N'-Tetramethyl-2,2'-oxybis[ethylamine];N,N,N',N'-Tetramethyl-3-oxapentane-1,5-diamine;N,N,N',N'-Tetramethylbisaminoethyl ether;NP 99;NSC 109887;Niax A 1;Niax A99;PC CAT NP 90;Texacat ZF 20;Toyocat ETS;ZF 20;Ethanamine,2,2'-oxybis[N,N-dimethyl-; |
Article Data | 28 |
2-(N,N-dimethylamino)ethanol
dimethyl amine
acetylene
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With potassium hydroxide In dibutyl ether at 100℃; for 5h; | 90.4% |
Conditions | Yield |
---|---|
In water at 175 - 180℃; for 3h; Temperature; Time; | 78.5% |
With 4-methyl-morpholine; ammonium tungstate at 145 - 155℃; for 15h; Reagent/catalyst; Autoclave; Inert atmosphere; Sealed tube; | 73.6% |
With sulfuric acid at 190℃; for 12h; Temperature; Reagent/catalyst; | 65% |
2-(N,N-dimethylamino)ethanol
N-Methyldiethanolamine
B
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With 4-methyl-morpholine; silica-alumina at 145 - 155℃; for 15h; Catalytic behavior; Reagent/catalyst; Time; Concentration; Temperature; Autoclave; Inert atmosphere; Sealed tube; Overall yield = 95.6 %; | A 76.4% B 75 g |
1-O-Dimethylaminoethyl-ethylenglykol
dimethyl amine
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With hydrogen at 220℃; under 15001.5 - 142514 Torr; for 8h; Temperature; Pressure; | 74.63% |
With hydrogen at 200℃; under 5931.67 Torr; Product distribution / selectivity; | 47 %Chromat. |
2-(N,N-dimethylamino)ethanol
2-(dimethylamino)ethyl chloride
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With sodium hydroxide; adogen 464 In tetrahydrofuran for 6h; Heating; | 35% |
dimethyl amine
3-oxa-1,5-dichloropentane
benzene
A
4-methyl-morpholine
B
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
at 140℃; |
dimethyl amine
3-oxa-1,5-dichloropentane
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With ethanol at 120℃; | |
With benzene at 140℃; |
sodium N,N-dimethylethanolamine
2-(dimethylamino)ethyl chloride
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With toluene |
2-(dimethylamino)ethyl chloride
benzene
A
2-(N,N-dimethylamino)ethanol
B
Bis<2-(N,N-dimethylamino)aethyl>aether
C
2-(dimethylamino)ethyl acetate
D
N-<2-(dimethylamino)ethyl>acetamide
Conditions | Yield |
---|---|
Produkt5: 1,2-Bis-dimethylamino-aethan; |
1-O-Dimethylaminoethyl-ethylenglykol
methylamine
A
4-methyl-morpholine
B
N,N,N'-trimethylbis(aminoethyl)ether
C
Bis<2-(N,N-dimethylamino)aethyl>aether
Conditions | Yield |
---|---|
With hydrogen at 195℃; under 11879 Torr; for 23.3h; Product distribution / selectivity; Compressed gas(es); | A 3.1 %Chromat. B 44.3 %Chromat. C 1.6 %Chromat. |
With hydrogen; potassium nitrate at 200℃; under 4395.7 Torr; Product distribution / selectivity; | |
With hydrogen at 200℃; under 4369.84 Torr; Product distribution / selectivity; |
The Molecular Structure of Bis(2-dimethylaminoethyl) ether (CAS NO.3033-62-3):
Empirical Formula: C8H20N2O
Molecular Weight: 160.2572
Appearance: A clear or yellow liquid
Nominal Mass: 160 Da
Average Mass: 160.2572 Da
Monoisotopic Mass: 160.157563 Da
Index of Refraction: 1.445
Molar Refractivity: 48.29 cm3
Molar Volume: 181.4 cm3
Surface Tension: 29.1 dyne/cm
Density: 0.883 g/cm3
Flash Point: 46.2 °C
Enthalpy of Vaporization: 43.1 kJ/mol
Boiling Point: 194.8 °C at 760 mmHg
Vapour Pressure: 0.433 mmHg at 25°C
Classification Code: Reproductive Effect; Skin / Eye Irritant; TWA (0.05 ppm); STEL (0.15 ppm); Skin / Eye Irritant; TWA (0.05 ppm); STEL (0.15 ppm); Skin
IUPAC: 2-(2-dimethylaminoethyloxy)-N,N-dimethylethanamine
Synonyms: Lupragen(r) n 205 ; Lupragen(r) n 206 ; Di-[2-(n,n-dimethylaminoethyl)]ether ; Dabco(r) 2039 ; Dabco(r) dc4000 ; Dabco(r) dc5582 ; Dabco(r) dc5598 ; Dabco(r) dc5599
1. | skn-rbt 500 mg open SEV | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 12/27/71 . | ||
2. | skn-rbt 100 mg/24H SEV | JTOTDO Journal of Toxicology, Cutaneous and Ocular Toxicology. 5 (1986),3. | ||
3. | eye-rbt 1 mg SEV | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 12/27/71 . | ||
4. | eye-rbt 250 µg/24H SEV | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986721. | ||
5. | orl-rat LD50:1070 mg/kg | JTOTDO Journal of Toxicology, Cutaneous and Ocular Toxicology. 5 (1986),3. | ||
6. | skn-rbt LD50:280 µL/kg | AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470. |
Bis(2-dimethylaminoethyl) ether (CAS NO.3033-62-3) was reported in EPA TSCA Inventory.
Poison by skin contact. Moderately toxic by ingestion. Experimental reproductive effects. A severe skin and eye irritant. See also ETHERS. When Bis(2-dimethylaminoethyl) ether was heated to decomposition, it emits toxic fumes of NOx.
Hazard Codes: T
Risk Statements: 20-22-24-34
R20: Harmful by inhalation
R22: Harmful if swallowed
R24: Toxic in contact with skin
R34: Causes burns
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2927 6.1/PG 2
WGK Germany: 2
RTECS: KR9460000
HazardClass: 3
PackingGroup: III
ACGIH TLV: TWA 0.05 ppm; STEL 0.15 ppm (skin))