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Bis(diethylamino)chlorophosphine

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Name

Bis(diethylamino)chlorophosphine

EINECS N/A
CAS No. 685-83-6 Density 1.002 g/mL at 25 °C(lit.)
PSA 20.07000 LogP 3.13570
Solubility reacts with water Melting Point N/A
Formula C8H20ClN2P Boiling Point 235.3 °C at 760 mmHg
Molecular Weight 210.687 Flash Point 96.1 °C
Transport Information UN 3265 8/PG 2 Appearance Colorless to light yellow liquid
Safety 23-26-36-36/37/39-45 Risk Codes 14-34
Molecular Structure Molecular Structure of 685-83-6 (BIS(DIETHYLAMINO)CHLOROPHOSPHINE) Hazard Symbols CorrosiveC
Synonyms

Phosphorodiamidouschloride, tetraethyl- (6CI,7CI,8CI,9CI);Bis(N,N-diethylamino)chlorophosphine;Bis(diethylamino)chlorophosphane;Bis(diethylamino)chlorophosphine;Chlorobis(diethylamino)phosphine;N,N,N',N'-Tetraethylphosphorodiamidouschloride;Tetraethyldiamidophosphorous chloride;Tetraethyldiaminochlorophosphite;Tetraethylphosphorodiamidous chloride;

Article Data 54

Bis(diethylamino)chlorophosphine Specification

The CAS register number of Bis(diethylamino)chlorophosphine is 685-83-6. It also can be called as N,N,N',N'-Tetraethylphosphorodiamidous chloride and the IUPAC name about this chemical is N-[chloro(diethylamino)phosphanyl]-N-ethylethanamine. The molecular formula about this chemical is C8H20ClN2P and molecular weight is 210.68. It belongs to the following product categories which include Ligand; Catalysis and Inorganic Chemistry; Phosphorus Compounds; Phosphorus Precursors and so on.

Physical properties about Bis(diethylamino)chlorophosphine are: (1)ACD/LogP: 3.52; (2)ACD/LogD (pH 5.5): 3.51; (3)ACD/LogD (pH 7.4): 3.52; (4)ACD/BCF (pH 5.5): 270.44; (5)ACD/BCF (pH 7.4): 278.21; (6)ACD/KOC (pH 5.5): 1900.79; (7)ACD/KOC (pH 7.4): 1955.42; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 6; (10)Polar Surface Area: 20.07Å2; (11)Flash Point: 96.1 °C; (12)Enthalpy of Vaporization: 47.2 kJ/mol; (13)Boiling Point: 235.3 °C at 760 mmHg; (14)Vapour Pressure: 0.0505 mmHg at 25°C.

Preparation: this chemical can be prepared by diethylamine. This reaction will need reagent PCl3 and solvent diethyl ether.

Uses of Bis(diethylamino)chlorophosphine: it can be used to produce phosphonous acid bis-diethylamide. This reaction will need reagent LiAlH4.

When you are using this chemical, please be cautious about it as the following:
This chemical can cause burns. It can react violently with water. When you are using it, please wear suitable protective clothing, gloves and eye/face protection and do not breathe vapour. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, please seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: ClP(N(CC)CC)N(CC)CC
(2)InChI: InChI=1/C8H20ClN2P/c1-5-10(6-2)12(9)11(7-3)8-4/h5-8H2,1-4H3
(3)InChIKey: JVEHJSIFWIIFHM-UHFFFAOYAS
(4)Std. InChI: InChI=1S/C8H20ClN2P/c1-5-10(6-2)12(9)11(7-3)8-4/h5-8H2,1-4H3
(5)Std. InChIKey: JVEHJSIFWIIFHM-UHFFFAOYSA-N

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