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Bis(triphenylsilyl) chromate

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Name

Bis(triphenylsilyl) chromate

EINECS 216-612-8
CAS No. 1624-02-8 Density N/A
PSA 52.60000 LogP 4.03120
Solubility N/A Melting Point 159 °C (dec.)(lit.)
Formula C36H30CrO4Si2 Boiling Point N/A
Molecular Weight 634.799 Flash Point N/A
Transport Information UN 2811 6.1/PG 3 Appearance N/A
Safety 53-45-60-61 Risk Codes 49-43-50/53
Molecular Structure Molecular Structure of 1624-02-8 (BIS(TRIPHENYLSILYL)CHROMATE  96) Hazard Symbols ToxicT,DangerousN
Synonyms

Silanol, triphenyl-, chromate(VI) (6CI,7CI);Silanol, triphenyl-, diester with chromic acid (H2CrO4)(8CI);Chromic acid (H2CrO4), bis(triphenylsilyl) ester;

 

Bis(triphenylsilyl) chromate Consensus Reports

Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community Right-To-Know List.

Bis(triphenylsilyl) chromate Standards and Recommendations

OSHA PEL: CL 0.1 mg(CrO3)/m3
ACGIH TLV: TWA 0.05 mg(CrO3)/m3
NIOSH REL: (Chromium(VI)): TWA 0.025 mg(Cr(VI))/m3; CL 0.05/15M

Bis(triphenylsilyl) chromate Analytical Methods

For occupational chemical analysis use NIOSH: Chromium Hexavalent 7024.

Bis(triphenylsilyl) chromate Specification

The Bis(triphenylsilyl) chromate, with the CAS registry number 1624-02-8, is also known as Chromic acid (H2CrO4), bis(triphenylsilyl) ester. It belongs to the product categories of Organometallics; Others; Oxidation; Synthetic Reagents. Its EINECS number is 216-612-8. This chemical's molecular formula is C36H30CrO4Si2 and molecular weight is 634.79. What's more, its systematic name is Dioxo[bis(triphenylsilanolato)]chromium. This chemical is stable at common pressure and temperature, and it should be sealed and stored in a ventilated and dry place. Moreover, it should be protected from light. It is commonly used as organic synthesis reagents.

Physical properties of Bis(triphenylsilyl) chromate are: (1)#H bond acceptors: 4; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 10; (4)Polar Surface Area: 52.6 Å2.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause sensitisation by skin contact and may cause cancer by inhalation. It is very toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). It should be avoided exposure, and you must obtain special instructions before use. This material and its container must be disposed of as hazardous waste. You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: O=[Cr](=O)(O[Si](c1ccccc1)(c2ccccc2)c3ccccc3)O[Si](c4ccccc4)(c5ccccc5)c6ccccc6
(2)Std. InChI: InChI=1S/2C18H15OSi.Cr.2O/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;;;/q2*-1;+2;;
(3)Std. InChIKey: AQLZCGLPNYEIDH-UHFFFAOYSA-N

The toxicity data is as follows:  

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin 710mg/kg (710mg/kg)   Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat LD50 oral 3360mg/kg (3360mg/kg)   Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.

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