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Bismuth pentafluoride

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Name

Bismuth pentafluoride

EINECS 232-125-3
CAS No. 7787-62-4 Density g/cm3
PSA 0.00000 LogP -14.98000
Solubility violent reaction with H2O to form BiF3 and ozone [MER06] Melting Point 550°C (subl.)
Formula BiF5 Boiling Point °Cat760mmHg
Molecular Weight 303.972 Flash Point °C
Transport Information N/A Appearance N/A
Safety An irritant poison via ingestion and inhalation routes. Decomposes vigorously and sometimes ignites on contact with moisture to yield O3 and bismuth trifluoride. Very dangerous. Reacts violently with water and petrolatum above 50°, and acids at room temperature, liberating much heat and ozone. When heated to decomposition it emits highly toxic fumes of F. See also FLUORIDES and OZONE. Risk Codes 8-34
Molecular Structure Molecular Structure of 7787-62-4 (Bismuth pentafluoride) Hazard Symbols O,C
Synonyms

bithmuth tribromide;bismuth (III) bromide;bismuth(III) chloride;Wismut(III)-bromid;tribromobismuthine;Bismuth pentafluoride;Bismuth tribromide;Bismuth bromide;bismuth fluoride;Bismuthine,tribromo;tribromobismuth;

Article Data 21

Bismuth pentafluoride Chemical Properties

IUPAC Name: pentafluorobismuth
EINECS: 232-125-3
CAS NO: 7787-62-4  
Molecular Formula Bismuth pentafluoride (CAS NO.7787-62-4): BiF
Molecular Weight: 303.9735 
Molecular Structure:

Bismuth pentafluoride Production

BiF5 can be prepared by reacting BiF3 with F2 at 500 °C.
BiF3 + F2 → BiF5

Bismuth pentafluoride Safety Profile

Hazard Codes: OxidizingO,CorrosiveC
Risk Statements: 8-34 
R8: Contact with combustible material may cause fire. 
R34: Causes burns.
Safety Statements: 17-26-27-36/37/39 
S17: Keep away from combustible material. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S27: Take off immediately all contaminated clothing. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3084 8/PG 1
WGK Germany: 3
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: II
An irritant poison via ingestion and inhalation routes. Decomposes vigorously and sometimes ignites on contact with moisture to yield O3 and bismuth trifluoride. Very dangerous. Reacts violently with water and petrolatum above 50°, and acids at room temperature, liberating much heat and ozone. When heated to decomposition it emits highly toxic fumes of F. See also FLUORIDES and OZONE.

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