- Bisphenol A
- Bisphenol A bis(2-hydroxyethyl)ether
- Bisphenol A bisallyl ether
- Bisphenol A diglycidyl ether
- BISPHENOL A DIGLYCIDYL ETHER, BROMINATED
- Bisphenol A diphosphate
- Bisphenol A disodium salt
- Bisphenol A epichlorohydrin polymer
- BISPHENOL A ETHOXYLATE DIMETHACRYLATE
- Bisphenol A-glycidyl methacrylate
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Cas Database |
| Name |
Bisphenol A-glycidyl methacrylate |
EINECS | 216-367-7 |
| CAS No. | 1565-94-2 | Density | 1.161 g/mL at 25 °C(lit.) |
| PSA | 111.52000 | LogP | 3.73050 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C29H36 O8 | Boiling Point | 670.3±55.0 °C(Predicted) |
| Molecular Weight | 512.6 | Flash Point | >230 °F |
| Transport Information | N/A | Appearance | N/A |
| Safety | Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors. | Risk Codes | 41-43 |
| Molecular Structure |
|
Hazard Symbols | Xi |
| Synonyms |
2-Propenoicacid, 2-methyl-, (1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)]ester (9CI);Methacrylic acid,isopropylidenebis[p-phenyleneoxy(2-hydroxytrimethylene)] ester (7CI);1,2-Propanediol, 3,3'-[isopropylidenebis(p-phenyleneoxy)]di-,1,1'-dimethacrylate (8CI);2,2-Bis(4-(2-hydroxy-3-methacryloxypropoxy)phenyl)propane;2,2-Bis[4-(2-hydroxy-3-methacryloyloxy-1-propoxy)phenyl]propane;2,2-Bis[4-(2-hydroxy-3-methacryloyloxypropyloxy)phenyl]propane;2,2-Bis[4-(3-methacryloxy-2-hydroxypropoxy)phenyl]propane;2,2-Bis[4-(3-methacryloyloxy-2-hydroxypropoxy)phenyl]propane;2,2-Bis[4-[2-hydroxy-3-(methacryloyloxy)propoxy]phenyl]propane;2,2-Bis[p-(3-methacryloxy-2-hydroxypropoxy)phenyl]propane;2,2-Bis[p-[2-hydroxy-3-(methacryloxy)propoxy]phenyl]propane;2,2'-Bis[4-(3-methacryloyloxy-2-hydroxypropoxy)phenyl]propane;BADGEdimethacrylate;Bis-GMA;Bisphenol A bis(2-hydroxy-3-methacryloxypropyl) ether;Bisphenol A bis(2-hydroxy-3-methacryloyloxypropyl ether);Bisphenol Adiglycidyl ether dimethacrylate;Bisphenol A diglycidyl methacrylate;BisphenolA glycidylmethacrylate;Craynor CN 151;D-GMA;Derakane 411-35;DionVER 44070-00;Dow 411-35;Ebecryl 610;Epoxy Ester 3000M;FW 484;Nupol 1629;Nupol 46-4005;RDX 26936;Seal Rite I;Synolite 46-4005; |
Article Data | 4 |
Bisphenol A-glycidyl methacrylate Synthetic route
- 79-41-4
poly(methacrylic acid)
- 1675-54-3
diphenylolpropane diglycidyl ether
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| Stage #1: poly(methacrylic acid); diphenylolpropane diglycidyl ether With 2,6-di-tert-butyl-4-methyl-phenol at 105 - 108℃; for 2.25h; Stage #2: With N,N'-dimethylbenzylamine at 105℃; for 21h; Stage #3: With triethyleneglycol dimethacrylate |
- 80-05-7
BPA
- 106-91-2
2,3-Epoxypropyl methacrylate
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| With N,N'-dimethylbenzylamine at 70℃; for 6h; Inert atmosphere; Green chemistry; |
- 80-62-6
methacrylic acid methyl ester
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: potassium cyanide; 2,4-dimethyl-6-tert-butylphenol / 2 h / 70 - 80 °C / Green chemistry 2: N,N'-dimethylbenzylamine / 6 h / 70 °C / Inert atmosphere; Green chemistry View Scheme |
- 80-05-7
BPA
- 80-62-6
methacrylic acid methyl ester
- 56-81-5
glycerol
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| Stage #1: BPA; glycerol With potassium carbonate; Diethyl carbonate at 110℃; for 18h; Stage #2: methacrylic acid methyl ester In dimethyl sulfoxide at 110℃; |
- 5581-32-8
3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol
- 80-62-6
methacrylic acid methyl ester
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| With potassium carbonate at 90℃; for 18h; Temperature; |
- 30674-80-7
2-Isocyanatoethyl methacrylate
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
- 106884-07-5
2,2-bis-4(3-methacryloxy-2-hydroxypropoxy)phenylpropane diurethane dimethacrylate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 40℃; for 24h; | 95% |
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
- poly[2-methacrylic acid 2-hydroxy-3-[4-(1-{4-[2-hydroxy-3-(methacryloyloxy)-propoxy]-phenyl}-1-methyl-ethyl)-phenoxy]-propyl ester], photocured stereolithography
poly[2-methacrylic acid 2-hydroxy-3-[4-(1-{4-[2-hydroxy-3-(methacryloyloxy)-propoxy]-phenyl}-1-methyl-ethyl)-phenoxy]-propyl ester], photocured stereolithography
| Conditions | Yield |
|---|---|
| With Camphorquinone UV-irradiation; |
- 109-16-0
triethyleneglycol dimethacrylate
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| With water; sodium dodecyl-sulfate; Camphorquinone Product distribution / selectivity; Irradiation with visible light; | |
| With water; sodium dodecyl-sulfate; N,N-bis-(2-hydroxyethyl)-P-toluidine; dibenzoyl peroxide Product distribution / selectivity; Irradiation with light; | |
| With sodium dodecyl-sulfate; N,N-bis-(2-hydroxyethyl)-P-toluidine; dibenzoyl peroxide Product distribution / selectivity; Irradiation with light; |
- 109-16-0
triethyleneglycol dimethacrylate
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| With ethyl p-dimethyaminolbenzoate; (1S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione at 40℃; for 13h; Reactivity; Under yellow light; |
- 109-16-0
triethyleneglycol dimethacrylate
- 1565-94-2
(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate
| Conditions | Yield |
|---|---|
| With ethyl p-dimethyaminolbenzoate; (1S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione at 40℃; for 13h; Reactivity; Under yellow light; |
Bisphenol A-glycidyl methacrylate Chemical Properties
Molecular Formula: C29H36O8
Molar mass: 512.59 g/mol
EINECS: 216-367-7
Density: 1.161 g/cm3
Flash Point: 214.6 °C
Index of Refraction: 1.542
Boiling Point: 670.3 °C at 760 mmHg
Vapour Pressure: 7E-19 mmHg at 25°C
Product categories of Boron trifluoride dihydrate (1565-94-2): Acrylic Monomers;Bisphenol Acrylics
Structure of Boron trifluoride dihydrate (1565-94-2):
XLogP3-AA: 5.1
H-Bond Donor: 2
H-Bond Acceptor: 8
Systematic Name: [2-Hydroxy-3-[4-[1-[4-[2-hydroxy-3-(2-methylprop-2-enoyloxy)propoxy]phenyl]-1-methyl-ethyl]phenoxy]propyl] 2-methylprop-2-enoate
SMILES: O=C(OCC(O)COc1ccc(cc1)C(c2ccc(OCC(O)COC(=O)\C(=C)C)cc2)(C)C)\C(=C)C
InChI: InChI=1/C29H36O8/c1-19(2)27(32)36-17-23(30)15-34-25-11-7-21(8-12-25)29(5,6)22-9-13-26(14-10-22)35-16-24(31)18-37-28(33)20(3)4/h7-14,23-24,30-31H,1,3,15-18H2,2,4-6H3
InChIKey: AMFGWXWBFGVCKG-UHFFFAOYAI
Std. InChI: InChI=1S/C29H36O8/c1-19(2)27(32)36-17-23(30)15-34-25-11-7-21(8-12-25)29(5,6)22-9-13-26(14-10-22)35-16-24(31)18-37-28(33)20(3)4/h7-14,23-24,30-31H,1,3,15-18H2,2,4-6H3
Std. InChIKey: AMFGWXWBFGVCKG-UHFFFAOYSA-N
Bisphenol A-glycidyl methacrylate Toxicity Data With Reference
| 1. | mic-sat 800 µLg/plate | TOLED5 Toxicology Letters. (Elsevier Scientific Publishing Co., P.O. Box 211, Amsterdam, Netherlands) V.1- 1977- 31 (Suppl),(1986),214. | ||
| 2. | dni-hmn-hla 80 µmol/L | MUREAV Mutation Research. 368 (1996),181. |
Bisphenol A-glycidyl methacrylate Consensus Reports
Reported in EPA TSCA Inventory.
Bisphenol A-glycidyl methacrylate Safety Profile
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes: Xi.gif){kind=small}
Risk Statements:
41: Risk of serious damage to eyes
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
Bisphenol A-glycidyl methacrylate Specification
Boron trifluoride dihydrate (1565-94-2) also can be called Silux ; Adaptic ; Panavia opaque ; Bis-gma ; 2,2-Propanediylbis(4,1-phenyleneoxy-2-hydroxy-3,1-propanediyl) bis(2-methylacrylate) ;and 2-propenoic acid, 2-methyl-, (1-methylethylidene)bis(4,1-phenyleneoxy-2-hydroxy-3,1-propanediyl) ester .
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